Tags

Type your tag names separated by a space and hit enter

Rhodium(NHC)-catalyzed amination of aryl bromides.
Org Lett. 2010 Apr 02; 12(7):1640-3.OL

Abstract

A rhodium-catalyzed amination reaction of aryl halides with amines has been developed with the use of a N-heterocyclic carbene (NHC) ligand (IiPr = 1,3-diisopropylimidazol-2-ylidene). The active metal species responsible for the reaction progress was identified. The developed procedure of the Rh-catalyzedN-arylation is convenient to carry out under mild reaction conditions displaying a wide range of substrate scope and high degree of functional group tolerance.

Links

Publisher Full Text (DOI)

Authors+Show Affiliations

Kim M
Department of Chemistry and Molecular-Level Interface Research Center, Korea Advanced Institute of Science & Technology (KAIST), Daejeon 305-701, Korea.
Chang S
No affiliation info available

MeSH

AminationCatalysisCrystallography, X-RayHydrocarbons, BrominatedModels, MolecularMolecular StructureOrganometallic CompoundsRhodiumStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

20205466

Citation

Kim, Min, and Sukbok Chang. "Rhodium(NHC)-catalyzed Amination of Aryl Bromides." Organic Letters, vol. 12, no. 7, 2010, pp. 1640-3.
Kim M, Chang S. Rhodium(NHC)-catalyzed amination of aryl bromides. Org Lett. 2010;12(7):1640-3.
Kim, M., & Chang, S. (2010). Rhodium(NHC)-catalyzed amination of aryl bromides. Organic Letters, 12(7), 1640-3. https://doi.org/10.1021/ol100437j
Kim M, Chang S. Rhodium(NHC)-catalyzed Amination of Aryl Bromides. Org Lett. 2010 Apr 2;12(7):1640-3. PubMed PMID: 20205466.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Rhodium(NHC)-catalyzed amination of aryl bromides. AU - Kim,Min, AU - Chang,Sukbok, PY - 2010/3/9/entrez PY - 2010/3/9/pubmed PY - 2010/6/25/medline SP - 1640 EP - 3 JF - Organic letters JO - Org Lett VL - 12 IS - 7 N2 - A rhodium-catalyzed amination reaction of aryl halides with amines has been developed with the use of a N-heterocyclic carbene (NHC) ligand (IiPr = 1,3-diisopropylimidazol-2-ylidene). The active metal species responsible for the reaction progress was identified. The developed procedure of the Rh-catalyzedN-arylation is convenient to carry out under mild reaction conditions displaying a wide range of substrate scope and high degree of functional group tolerance. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/20205466/Rhodium_NHC__catalyzed_amination_of_aryl_bromides_ L2 - https://doi.org/10.1021/ol100437j DB - PRIME DP - Unbound Medicine ER -