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Rhodium-catalyzed oxidative coupling/cyclization of 2-phenylindoles with alkynes via C-H and N-H bond cleavages with air as the oxidant.
Org Lett. 2010 May 07; 12(9):2068-71.OL

Abstract

The straightforward and efficient synthesis of indolo[2,1-a]isoquinoline derivatives has been achieved by the rhodium-catalyzed aerobic oxidative coupling/cyclization of 2-phenylindoles with alkynes. Some of the polycyclic products exhibit solid-state fluorescence.

Authors+Show Affiliations

Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.No affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

20377234

Citation

Morimoto, Keisuke, et al. "Rhodium-catalyzed Oxidative Coupling/cyclization of 2-phenylindoles With Alkynes Via C-H and N-H Bond Cleavages With Air as the Oxidant." Organic Letters, vol. 12, no. 9, 2010, pp. 2068-71.
Morimoto K, Hirano K, Satoh T, et al. Rhodium-catalyzed oxidative coupling/cyclization of 2-phenylindoles with alkynes via C-H and N-H bond cleavages with air as the oxidant. Org Lett. 2010;12(9):2068-71.
Morimoto, K., Hirano, K., Satoh, T., & Miura, M. (2010). Rhodium-catalyzed oxidative coupling/cyclization of 2-phenylindoles with alkynes via C-H and N-H bond cleavages with air as the oxidant. Organic Letters, 12(9), 2068-71. https://doi.org/10.1021/ol100560k
Morimoto K, et al. Rhodium-catalyzed Oxidative Coupling/cyclization of 2-phenylindoles With Alkynes Via C-H and N-H Bond Cleavages With Air as the Oxidant. Org Lett. 2010 May 7;12(9):2068-71. PubMed PMID: 20377234.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Rhodium-catalyzed oxidative coupling/cyclization of 2-phenylindoles with alkynes via C-H and N-H bond cleavages with air as the oxidant. AU - Morimoto,Keisuke, AU - Hirano,Koji, AU - Satoh,Tetsuya, AU - Miura,Masahiro, PY - 2010/4/10/entrez PY - 2010/4/10/pubmed PY - 2010/8/3/medline SP - 2068 EP - 71 JF - Organic letters JO - Org Lett VL - 12 IS - 9 N2 - The straightforward and efficient synthesis of indolo[2,1-a]isoquinoline derivatives has been achieved by the rhodium-catalyzed aerobic oxidative coupling/cyclization of 2-phenylindoles with alkynes. Some of the polycyclic products exhibit solid-state fluorescence. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/20377234/Rhodium_catalyzed_oxidative_coupling/cyclization_of_2_phenylindoles_with_alkynes_via_C_H_and_N_H_bond_cleavages_with_air_as_the_oxidant_ L2 - https://doi.org/10.1021/ol100560k DB - PRIME DP - Unbound Medicine ER -