Rhodium catalysed chemo- and stereoselective arylative and alkenylative cyclisation reactions of unsymmetric diynes containing a terminal alkyne moiety with organoboronic acids.Org Biomol Chem. 2010 May 07; 8(9):2060-7.OB
Abstract
Unsymmetric diynes possessing a terminal alkyne moiety reacted with organoboronic acids both chemo- and stereoselectively to afford arylated or alkenylated exocyclic dienes by catalysis from the [Rh(cod)OCH(3)](2) complex. The use of a polar protic solvent, e.g. CH(3)OH is required for the success of the process under mild conditions.
Links
MeSH
Pub Type(s)
Journal Article
Research Support, Non-U.S. Gov't
Language
eng
PubMed ID
20401382
Citation
Artok, Levent, et al. "Rhodium Catalysed Chemo- and Stereoselective Arylative and Alkenylative Cyclisation Reactions of Unsymmetric Diynes Containing a Terminal Alkyne Moiety With Organoboronic Acids." Organic & Biomolecular Chemistry, vol. 8, no. 9, 2010, pp. 2060-7.
Artok L, Kuş M, Urer BN, et al. Rhodium catalysed chemo- and stereoselective arylative and alkenylative cyclisation reactions of unsymmetric diynes containing a terminal alkyne moiety with organoboronic acids. Org Biomol Chem. 2010;8(9):2060-7.
Artok, L., Kuş, M., Urer, B. N., Türkmen, G., & Aksin-Artok, O. (2010). Rhodium catalysed chemo- and stereoselective arylative and alkenylative cyclisation reactions of unsymmetric diynes containing a terminal alkyne moiety with organoboronic acids. Organic & Biomolecular Chemistry, 8(9), 2060-7. https://doi.org/10.1039/b926553h
Artok L, et al. Rhodium Catalysed Chemo- and Stereoselective Arylative and Alkenylative Cyclisation Reactions of Unsymmetric Diynes Containing a Terminal Alkyne Moiety With Organoboronic Acids. Org Biomol Chem. 2010 May 7;8(9):2060-7. PubMed PMID: 20401382.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR
T1 - Rhodium catalysed chemo- and stereoselective arylative and alkenylative cyclisation reactions of unsymmetric diynes containing a terminal alkyne moiety with organoboronic acids.
AU - Artok,Levent,
AU - Kuş,Melih,
AU - Urer,Bağdagül N,
AU - Türkmen,Gülşah,
AU - Aksin-Artok,Ozge,
Y1 - 2010/03/01/
PY - 2010/4/20/entrez
PY - 2010/4/20/pubmed
PY - 2010/7/16/medline
SP - 2060
EP - 7
JF - Organic & biomolecular chemistry
JO - Org Biomol Chem
VL - 8
IS - 9
N2 - Unsymmetric diynes possessing a terminal alkyne moiety reacted with organoboronic acids both chemo- and stereoselectively to afford arylated or alkenylated exocyclic dienes by catalysis from the [Rh(cod)OCH(3)](2) complex. The use of a polar protic solvent, e.g. CH(3)OH is required for the success of the process under mild conditions.
SN - 1477-0539
UR - https://www.unboundmedicine.com/medline/citation/20401382/Rhodium_catalysed_chemo__and_stereoselective_arylative_and_alkenylative_cyclisation_reactions_of_unsymmetric_diynes_containing_a_terminal_alkyne_moiety_with_organoboronic_acids_
L2 - https://doi.org/10.1039/b926553h
DB - PRIME
DP - Unbound Medicine
ER -