Tags

Type your tag names separated by a space and hit enter

Primary amine-metal Lewis acid bifunctional catalysts based on a simple bidentate ligand: direct asymmetric aldol reaction.
Chem Commun (Camb). 2011 Jan 07; 47(1):224-6.CC

Abstract

A novel class of primary amine-metal Lewis acid bifunctional catalysts based on a bidentate ligand was developed. These catalysts were highly efficient in catalyzing the direct asymmetric aldol reactions of ketones offering excellent stereoselectivity. The aldol reactions required a low catalyst loading (2.5 mol%), and were water compatible.

Links

Publisher Full Text (DOI)

Authors+Show Affiliations

Daka P
Department of Chemistry and Biochemistry, Miami University, Oxford, OH 45056, US.
Xu Z
No affiliation info available
Alexa A
No affiliation info available
Wang H
No affiliation info available

MeSH

AlcoholsAldehydesAminesCatalysisCopperKetonesLigandsMolecular StructureStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

20563349

Citation

Daka, Philias, et al. "Primary Amine-metal Lewis Acid Bifunctional Catalysts Based On a Simple Bidentate Ligand: Direct Asymmetric Aldol Reaction." Chemical Communications (Cambridge, England), vol. 47, no. 1, 2011, pp. 224-6.
Daka P, Xu Z, Alexa A, et al. Primary amine-metal Lewis acid bifunctional catalysts based on a simple bidentate ligand: direct asymmetric aldol reaction. Chem Commun (Camb). 2011;47(1):224-6.
Daka, P., Xu, Z., Alexa, A., & Wang, H. (2011). Primary amine-metal Lewis acid bifunctional catalysts based on a simple bidentate ligand: direct asymmetric aldol reaction. Chemical Communications (Cambridge, England), 47(1), 224-6. https://doi.org/10.1039/c0cc00917b
Daka P, et al. Primary Amine-metal Lewis Acid Bifunctional Catalysts Based On a Simple Bidentate Ligand: Direct Asymmetric Aldol Reaction. Chem Commun (Camb). 2011 Jan 7;47(1):224-6. PubMed PMID: 20563349.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Primary amine-metal Lewis acid bifunctional catalysts based on a simple bidentate ligand: direct asymmetric aldol reaction. AU - Daka,Philias, AU - Xu,Zhenghu, AU - Alexa,Alexandru, AU - Wang,Hong, Y1 - 2010/06/21/ PY - 2010/6/22/entrez PY - 2010/6/22/pubmed PY - 2011/3/23/medline SP - 224 EP - 6 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) VL - 47 IS - 1 N2 - A novel class of primary amine-metal Lewis acid bifunctional catalysts based on a bidentate ligand was developed. These catalysts were highly efficient in catalyzing the direct asymmetric aldol reactions of ketones offering excellent stereoselectivity. The aldol reactions required a low catalyst loading (2.5 mol%), and were water compatible. SN - 1364-548X UR - https://www.unboundmedicine.com/medline/citation/20563349/Primary_amine_metal_Lewis_acid_bifunctional_catalysts_based_on_a_simple_bidentate_ligand:_direct_asymmetric_aldol_reaction_ L2 - https://doi.org/10.1039/c0cc00917b DB - PRIME DP - Unbound Medicine ER -