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Bimetallic nickel aluminum mediated para-selective alkenylation of pyridine: direct observation of eta2,eta1-pyridine Ni(0)-Al(III) intermediates prior to C-H bond activation.
J Am Chem Soc. 2010 Sep 01; 132(34):11887-9.JA

Abstract

We have presented new amino-NHC Ni-Al complex mediated para C-H bond activation for pyridine and quinolin, and isolated for the first time the intermediate structure of a bimetallic eta(2),eta(1)-pyridine nickel aluminum complex prior to its C-H activation, which serves as key evidence for bimetallic catalysis.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Tsai CC
Institute of Chemistry, Academia Sinica, Nangang, Taipei, Taiwan, Republic of China.
Shih WC
No affiliation info available
Fang CH
No affiliation info available
Li CY
No affiliation info available
Ong TG
No affiliation info available
Yap GP
No affiliation info available

MeSH

AlkylationAlkynesAluminumCatalysisCrystallography, X-RayModels, MolecularMolecular StructureNickelOrganometallic CompoundsPyridinesQuinolines

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

20690626

Citation

Tsai, Chung-Chih, et al. "Bimetallic Nickel Aluminum Mediated Para-selective Alkenylation of Pyridine: Direct Observation of Eta2,eta1-pyridine Ni(0)-Al(III) Intermediates Prior to C-H Bond Activation." Journal of the American Chemical Society, vol. 132, no. 34, 2010, pp. 11887-9.
Tsai CC, Shih WC, Fang CH, et al. Bimetallic nickel aluminum mediated para-selective alkenylation of pyridine: direct observation of eta2,eta1-pyridine Ni(0)-Al(III) intermediates prior to C-H bond activation. J Am Chem Soc. 2010;132(34):11887-9.
Tsai, C. C., Shih, W. C., Fang, C. H., Li, C. Y., Ong, T. G., & Yap, G. P. (2010). Bimetallic nickel aluminum mediated para-selective alkenylation of pyridine: direct observation of eta2,eta1-pyridine Ni(0)-Al(III) intermediates prior to C-H bond activation. Journal of the American Chemical Society, 132(34), 11887-9. https://doi.org/10.1021/ja1061246
Tsai CC, et al. Bimetallic Nickel Aluminum Mediated Para-selective Alkenylation of Pyridine: Direct Observation of Eta2,eta1-pyridine Ni(0)-Al(III) Intermediates Prior to C-H Bond Activation. J Am Chem Soc. 2010 Sep 1;132(34):11887-9. PubMed PMID: 20690626.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Bimetallic nickel aluminum mediated para-selective alkenylation of pyridine: direct observation of eta2,eta1-pyridine Ni(0)-Al(III) intermediates prior to C-H bond activation. AU - Tsai,Chung-Chih, AU - Shih,Wei-Chih, AU - Fang,Cyong-Hui, AU - Li,Chia-Yi, AU - Ong,Tiow-Gan, AU - Yap,Glenn P A, PY - 2010/8/10/entrez PY - 2010/8/10/pubmed PY - 2010/12/14/medline SP - 11887 EP - 9 JF - Journal of the American Chemical Society JO - J Am Chem Soc VL - 132 IS - 34 N2 - We have presented new amino-NHC Ni-Al complex mediated para C-H bond activation for pyridine and quinolin, and isolated for the first time the intermediate structure of a bimetallic eta(2),eta(1)-pyridine nickel aluminum complex prior to its C-H activation, which serves as key evidence for bimetallic catalysis. SN - 1520-5126 UR - https://www.unboundmedicine.com/medline/citation/20690626/Bimetallic_nickel_aluminum_mediated_para_selective_alkenylation_of_pyridine:_direct_observation_of_eta2eta1_pyridine_Ni_0__Al_III__intermediates_prior_to_C_H_bond_activation_ L2 - https://doi.org/10.1021/ja1061246 DB - PRIME DP - Unbound Medicine ER -