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Organocatalytic diimide reduction of enamides in water.
Chem Commun (Camb). 2011 Jan 07; 47(1):280-2.CC

Abstract

Bridged flavinium organocatalysts have displayed efficacy in the diimide mediated reduction of enamides in aqueous conditions. This represents the first diimide reduction of an electron rich alkene and offers a clean alternative to the use of alkylating agents for N-alkylation.

Links

Publisher Full Text (DOI)

Authors+Show Affiliations

Marsh BJ
Department of Chemistry, University of Bath, Bath, BA2 7AY, UK.
Heath EL
No affiliation info available
Carbery DR
No affiliation info available

MeSH

AlkanesAlkenesAlkylationAmidesCatalysisElectronsFlavinsImidesMolecular StructureOxidation-ReductionStereoisomerismWater

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

20714574

Citation

Marsh, Barrie J., et al. "Organocatalytic Diimide Reduction of Enamides in Water." Chemical Communications (Cambridge, England), vol. 47, no. 1, 2011, pp. 280-2.
Marsh BJ, Heath EL, Carbery DR. Organocatalytic diimide reduction of enamides in water. Chem Commun (Camb). 2011;47(1):280-2.
Marsh, B. J., Heath, E. L., & Carbery, D. R. (2011). Organocatalytic diimide reduction of enamides in water. Chemical Communications (Cambridge, England), 47(1), 280-2. https://doi.org/10.1039/c0cc02272a
Marsh BJ, Heath EL, Carbery DR. Organocatalytic Diimide Reduction of Enamides in Water. Chem Commun (Camb). 2011 Jan 7;47(1):280-2. PubMed PMID: 20714574.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Organocatalytic diimide reduction of enamides in water. AU - Marsh,Barrie J, AU - Heath,Emma L, AU - Carbery,David R, Y1 - 2010/08/16/ PY - 2010/8/18/entrez PY - 2010/8/18/pubmed PY - 2011/3/23/medline SP - 280 EP - 2 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) VL - 47 IS - 1 N2 - Bridged flavinium organocatalysts have displayed efficacy in the diimide mediated reduction of enamides in aqueous conditions. This represents the first diimide reduction of an electron rich alkene and offers a clean alternative to the use of alkylating agents for N-alkylation. SN - 1364-548X UR - https://www.unboundmedicine.com/medline/citation/20714574/Organocatalytic_diimide_reduction_of_enamides_in_water_ L2 - https://doi.org/10.1039/c0cc02272a DB - PRIME DP - Unbound Medicine ER -