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Palladium(II)-catalyzed asymmetric hydrophosphination of enones: efficient access to chiral tertiary phosphines.
Chem Commun (Camb). 2010 Oct 07; 46(37):6950-2.CC

Abstract

Chiral tertiary phosphines were synthesized by asymmetric hydrophosphination of aromatic enones catalyzed by an organopalladium complex with high yields and stereoselectivity. The procedure offers practical access to chiral tertiary phosphines.

Links

Publisher Full Text (DOI)

Authors+Show Affiliations

Huang Y
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore.
Pullarkat SA
No affiliation info available
Li Y
No affiliation info available
Leung PH
No affiliation info available

MeSH

AlkenesCatalysisKetonesMolecular StructureOrganometallic CompoundsPalladiumPhosphinesStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

20730193

Citation

Huang, Yinhua, et al. "Palladium(II)-catalyzed Asymmetric Hydrophosphination of Enones: Efficient Access to Chiral Tertiary Phosphines." Chemical Communications (Cambridge, England), vol. 46, no. 37, 2010, pp. 6950-2.
Huang Y, Pullarkat SA, Li Y, et al. Palladium(II)-catalyzed asymmetric hydrophosphination of enones: efficient access to chiral tertiary phosphines. Chem Commun (Camb). 2010;46(37):6950-2.
Huang, Y., Pullarkat, S. A., Li, Y., & Leung, P. H. (2010). Palladium(II)-catalyzed asymmetric hydrophosphination of enones: efficient access to chiral tertiary phosphines. Chemical Communications (Cambridge, England), 46(37), 6950-2. https://doi.org/10.1039/c0cc00925c
Huang Y, et al. Palladium(II)-catalyzed Asymmetric Hydrophosphination of Enones: Efficient Access to Chiral Tertiary Phosphines. Chem Commun (Camb). 2010 Oct 7;46(37):6950-2. PubMed PMID: 20730193.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Palladium(II)-catalyzed asymmetric hydrophosphination of enones: efficient access to chiral tertiary phosphines. AU - Huang,Yinhua, AU - Pullarkat,Sumod A, AU - Li,Yongxin, AU - Leung,Pak-Hing, Y1 - 2010/08/23/ PY - 2010/8/24/entrez PY - 2010/8/24/pubmed PY - 2010/12/22/medline SP - 6950 EP - 2 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) VL - 46 IS - 37 N2 - Chiral tertiary phosphines were synthesized by asymmetric hydrophosphination of aromatic enones catalyzed by an organopalladium complex with high yields and stereoselectivity. The procedure offers practical access to chiral tertiary phosphines. SN - 1364-548X UR - https://www.unboundmedicine.com/medline/citation/20730193/Palladium_II__catalyzed_asymmetric_hydrophosphination_of_enones:_efficient_access_to_chiral_tertiary_phosphines_ DB - PRIME DP - Unbound Medicine ER -