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Studies in catalytic C-H amination involving nitrene C-H insertion.
Dalton Trans. 2010 Nov 21; 39(43):10401-13.DT

Abstract

Stereoselective catalytic intermolecular C-H amination of complex molecules is reported. Site-selective functionalizations occur with very good yields up to 91% and excellent d.e.s up to 99%. However, the precise nature of the nitrene C-H insertion remains a matter of debate despite several physical organic experiments.

Authors+Show Affiliations

Institut de Chimie des Substances Naturelles, UPR 2301 CNRS, Centre de Recherches de Gif, Avenue de la Terrasse, 91198, Gif-sur-Yvette Cedex, France.No affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

20931128

Citation

Collet, Florence, et al. "Studies in Catalytic C-H Amination Involving Nitrene C-H Insertion." Dalton Transactions (Cambridge, England : 2003), vol. 39, no. 43, 2010, pp. 10401-13.
Collet F, Lescot C, Liang C, et al. Studies in catalytic C-H amination involving nitrene C-H insertion. Dalton Trans. 2010;39(43):10401-13.
Collet, F., Lescot, C., Liang, C., & Dauban, P. (2010). Studies in catalytic C-H amination involving nitrene C-H insertion. Dalton Transactions (Cambridge, England : 2003), 39(43), 10401-13. https://doi.org/10.1039/c0dt00283f
Collet F, et al. Studies in Catalytic C-H Amination Involving Nitrene C-H Insertion. Dalton Trans. 2010 Nov 21;39(43):10401-13. PubMed PMID: 20931128.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Studies in catalytic C-H amination involving nitrene C-H insertion. AU - Collet,Florence, AU - Lescot,Camille, AU - Liang,Chungen, AU - Dauban,Philippe, Y1 - 2010/10/08/ PY - 2010/10/9/entrez PY - 2010/10/12/pubmed PY - 2011/2/9/medline SP - 10401 EP - 13 JF - Dalton transactions (Cambridge, England : 2003) JO - Dalton Trans VL - 39 IS - 43 N2 - Stereoselective catalytic intermolecular C-H amination of complex molecules is reported. Site-selective functionalizations occur with very good yields up to 91% and excellent d.e.s up to 99%. However, the precise nature of the nitrene C-H insertion remains a matter of debate despite several physical organic experiments. SN - 1477-9234 UR - https://www.unboundmedicine.com/medline/citation/20931128/Studies_in_catalytic_C_H_amination_involving_nitrene_C_H_insertion_ L2 - https://doi.org/10.1039/c0dt00283f DB - PRIME DP - Unbound Medicine ER -