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Enantioselective copper-catalyzed intramolecular O-H insertion: an efficient approach to chiral 2-carboxy cyclic ethers.
J Am Chem Soc. 2010 Nov 24; 132(46):16374-6.JA

Abstract

A copper-catalyzed asymmetric intramolecular O-H insertion of ω-hydroxy-α-diazoesters has been accomplished by using chiral spiro bisoxazoline ligands. This highly enantioselective intramolecular O-H insertion reaction provides an efficient approach to a variety of synthetically important chiral 2-carboxy cyclic ethers with different ring sizes as well as substitution patterns.

Authors+Show Affiliations

State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071, China.No affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

21033664

Citation

Zhu, Shou-Fei, et al. "Enantioselective Copper-catalyzed Intramolecular O-H Insertion: an Efficient Approach to Chiral 2-carboxy Cyclic Ethers." Journal of the American Chemical Society, vol. 132, no. 46, 2010, pp. 16374-6.
Zhu SF, Song XG, Li Y, et al. Enantioselective copper-catalyzed intramolecular O-H insertion: an efficient approach to chiral 2-carboxy cyclic ethers. J Am Chem Soc. 2010;132(46):16374-6.
Zhu, S. F., Song, X. G., Li, Y., Cai, Y., & Zhou, Q. L. (2010). Enantioselective copper-catalyzed intramolecular O-H insertion: an efficient approach to chiral 2-carboxy cyclic ethers. Journal of the American Chemical Society, 132(46), 16374-6. https://doi.org/10.1021/ja1078464
Zhu SF, et al. Enantioselective Copper-catalyzed Intramolecular O-H Insertion: an Efficient Approach to Chiral 2-carboxy Cyclic Ethers. J Am Chem Soc. 2010 Nov 24;132(46):16374-6. PubMed PMID: 21033664.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Enantioselective copper-catalyzed intramolecular O-H insertion: an efficient approach to chiral 2-carboxy cyclic ethers. AU - Zhu,Shou-Fei, AU - Song,Xiao-Guang, AU - Li,Yu, AU - Cai,Yan, AU - Zhou,Qi-Lin, Y1 - 2010/10/29/ PY - 2010/11/2/entrez PY - 2010/11/3/pubmed PY - 2011/3/9/medline SP - 16374 EP - 6 JF - Journal of the American Chemical Society JO - J Am Chem Soc VL - 132 IS - 46 N2 - A copper-catalyzed asymmetric intramolecular O-H insertion of ω-hydroxy-α-diazoesters has been accomplished by using chiral spiro bisoxazoline ligands. This highly enantioselective intramolecular O-H insertion reaction provides an efficient approach to a variety of synthetically important chiral 2-carboxy cyclic ethers with different ring sizes as well as substitution patterns. SN - 1520-5126 UR - https://www.unboundmedicine.com/medline/citation/21033664/Enantioselective_copper_catalyzed_intramolecular_O_H_insertion:_an_efficient_approach_to_chiral_2_carboxy_cyclic_ethers_ L2 - https://doi.org/10.1021/ja1078464 DB - PRIME DP - Unbound Medicine ER -