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Catalytic C-H functionalization by metalloporphyrins: recent developments and future directions.
Chem Soc Rev. 2011 Apr; 40(4):1899-909.CS

Abstract

Metalloporphyrins are a class of versatile catalysts with the capability to functionalize saturated C-H bonds via several well-defined atom/group transfer processes, including oxene, nitrene, and carbene C-H insertions. The corresponding hydroxylation, amination, and alkylation reactions provide direct approaches for the catalytic conversion of abundant hydrocarbons into value-added functional molecules through C-O, C-N, and C-C bond formations, respectively. This tutorial review describes metalloporphyrin-based catalytic systems for the functionalization of different types of sp(3) C-H bonds, both inter- and intramolecularly, including challenging primary C-H bonds. Additional features of metalloporphyrin-catalyzed C-H functionalization include unusual selectivities and high turnover numbers.

Authors+Show Affiliations

Department of Chemistry, University of South Florida, Tampa, Florida 33620-5250, USA.No affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't
Review

Language

eng

PubMed ID

21088785

Citation

Lu, Hongjian, and X Peter Zhang. "Catalytic C-H Functionalization By Metalloporphyrins: Recent Developments and Future Directions." Chemical Society Reviews, vol. 40, no. 4, 2011, pp. 1899-909.
Lu H, Zhang XP. Catalytic C-H functionalization by metalloporphyrins: recent developments and future directions. Chem Soc Rev. 2011;40(4):1899-909.
Lu, H., & Zhang, X. P. (2011). Catalytic C-H functionalization by metalloporphyrins: recent developments and future directions. Chemical Society Reviews, 40(4), 1899-909. https://doi.org/10.1039/c0cs00070a
Lu H, Zhang XP. Catalytic C-H Functionalization By Metalloporphyrins: Recent Developments and Future Directions. Chem Soc Rev. 2011;40(4):1899-909. PubMed PMID: 21088785.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Catalytic C-H functionalization by metalloporphyrins: recent developments and future directions. AU - Lu,Hongjian, AU - Zhang,X Peter, Y1 - 2010/11/19/ PY - 2010/11/20/entrez PY - 2010/11/23/pubmed PY - 2011/7/2/medline SP - 1899 EP - 909 JF - Chemical Society reviews JO - Chem Soc Rev VL - 40 IS - 4 N2 - Metalloporphyrins are a class of versatile catalysts with the capability to functionalize saturated C-H bonds via several well-defined atom/group transfer processes, including oxene, nitrene, and carbene C-H insertions. The corresponding hydroxylation, amination, and alkylation reactions provide direct approaches for the catalytic conversion of abundant hydrocarbons into value-added functional molecules through C-O, C-N, and C-C bond formations, respectively. This tutorial review describes metalloporphyrin-based catalytic systems for the functionalization of different types of sp(3) C-H bonds, both inter- and intramolecularly, including challenging primary C-H bonds. Additional features of metalloporphyrin-catalyzed C-H functionalization include unusual selectivities and high turnover numbers. SN - 1460-4744 UR - https://www.unboundmedicine.com/medline/citation/21088785/Catalytic_C_H_functionalization_by_metalloporphyrins:_recent_developments_and_future_directions_ L2 - https://doi.org/10.1039/c0cs00070a DB - PRIME DP - Unbound Medicine ER -
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