Highly chemoselective nickel-catalyzed three-component cross-trimerization between two distinct terminal alkynes and an internal alkyne.Org Lett. 2011 Jan 07; 13(1):122-5.OL
Abstract
The highly chemo-, regio-, and stereoselective three-component cross-trimerization reaction between triisopropylsilylacetylene, diarylacetylene, and a terminal alkyne was achieved by Ni(cod)(2)/P(p-CF(3)C(6)H(4))(3) catalyst at room temperature via selective C-H oxidative addition of the terminal silylacetylene. The reaction is applicable for various diarylacetylenes and terminal alkynes to yield the corresponding 1,3-diene-5-yne compounds.
Links
Pub Type(s)
Journal Article
Language
eng
PubMed ID
21133396
Citation
Ogata, Kenichi, et al. "Highly Chemoselective Nickel-catalyzed Three-component Cross-trimerization Between Two Distinct Terminal Alkynes and an Internal Alkyne." Organic Letters, vol. 13, no. 1, 2011, pp. 122-5.
Ogata K, Atsuumi Y, Fukuzawa S. Highly chemoselective nickel-catalyzed three-component cross-trimerization between two distinct terminal alkynes and an internal alkyne. Org Lett. 2011;13(1):122-5.
Ogata, K., Atsuumi, Y., & Fukuzawa, S. (2011). Highly chemoselective nickel-catalyzed three-component cross-trimerization between two distinct terminal alkynes and an internal alkyne. Organic Letters, 13(1), 122-5. https://doi.org/10.1021/ol102687p
Ogata K, Atsuumi Y, Fukuzawa S. Highly Chemoselective Nickel-catalyzed Three-component Cross-trimerization Between Two Distinct Terminal Alkynes and an Internal Alkyne. Org Lett. 2011 Jan 7;13(1):122-5. PubMed PMID: 21133396.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR
T1 - Highly chemoselective nickel-catalyzed three-component cross-trimerization between two distinct terminal alkynes and an internal alkyne.
AU - Ogata,Kenichi,
AU - Atsuumi,Yuka,
AU - Fukuzawa,Shin-Ichi,
Y1 - 2010/12/06/
PY - 2010/12/8/entrez
PY - 2010/12/8/pubmed
PY - 2010/12/8/medline
SP - 122
EP - 5
JF - Organic letters
JO - Org Lett
VL - 13
IS - 1
N2 - The highly chemo-, regio-, and stereoselective three-component cross-trimerization reaction between triisopropylsilylacetylene, diarylacetylene, and a terminal alkyne was achieved by Ni(cod)(2)/P(p-CF(3)C(6)H(4))(3) catalyst at room temperature via selective C-H oxidative addition of the terminal silylacetylene. The reaction is applicable for various diarylacetylenes and terminal alkynes to yield the corresponding 1,3-diene-5-yne compounds.
SN - 1523-7052
UR - https://www.unboundmedicine.com/medline/citation/21133396/Highly_chemoselective_nickel_catalyzed_three_component_cross_trimerization_between_two_distinct_terminal_alkynes_and_an_internal_alkyne_
L2 - https://doi.org/10.1021/ol102687p
DB - PRIME
DP - Unbound Medicine
ER -
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