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Asymmetric synthesis of axially chiral biaryl diphosphine ligands by rhodium-catalyzed enantioselective intramolecular double [2 + 2 + 2] cycloaddition.
Org Lett. 2011 Feb 04; 13(3):362-5.OL

Abstract

The concise synthesis of axially chiral biaryl diphosphine ligands by the rhodium-catalyzed intramolecular [2 + 2 + 2] cycloaddition of hexayne diphosphine oxides has been achieved. These new chiral diphosphine ligands could be employed as a ligand for the rhodium-catalyzed asymmetric catalyses.

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Authors+Show Affiliations

Mori F
Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan.
Fukawa N
No affiliation info available
Noguchi K
No affiliation info available
Tanaka K
No affiliation info available

Pub Type(s)

Journal Article

Language

eng

PubMed ID

21186789

Citation

Mori, Fumiya, et al. "Asymmetric Synthesis of Axially Chiral Biaryl Diphosphine Ligands By Rhodium-catalyzed Enantioselective Intramolecular Double [2 + 2 + 2] Cycloaddition." Organic Letters, vol. 13, no. 3, 2011, pp. 362-5.
Mori F, Fukawa N, Noguchi K, et al. Asymmetric synthesis of axially chiral biaryl diphosphine ligands by rhodium-catalyzed enantioselective intramolecular double [2 + 2 + 2] cycloaddition. Org Lett. 2011;13(3):362-5.
Mori, F., Fukawa, N., Noguchi, K., & Tanaka, K. (2011). Asymmetric synthesis of axially chiral biaryl diphosphine ligands by rhodium-catalyzed enantioselective intramolecular double [2 + 2 + 2] cycloaddition. Organic Letters, 13(3), 362-5. https://doi.org/10.1021/ol102927y
Mori F, et al. Asymmetric Synthesis of Axially Chiral Biaryl Diphosphine Ligands By Rhodium-catalyzed Enantioselective Intramolecular Double [2 + 2 + 2] Cycloaddition. Org Lett. 2011 Feb 4;13(3):362-5. PubMed PMID: 21186789.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Asymmetric synthesis of axially chiral biaryl diphosphine ligands by rhodium-catalyzed enantioselective intramolecular double [2 + 2 + 2] cycloaddition. AU - Mori,Fumiya, AU - Fukawa,Naohiro, AU - Noguchi,Keiichi, AU - Tanaka,Ken, Y1 - 2010/12/27/ PY - 2010/12/29/entrez PY - 2010/12/29/pubmed PY - 2010/12/29/medline SP - 362 EP - 5 JF - Organic letters JO - Org Lett VL - 13 IS - 3 N2 - The concise synthesis of axially chiral biaryl diphosphine ligands by the rhodium-catalyzed intramolecular [2 + 2 + 2] cycloaddition of hexayne diphosphine oxides has been achieved. These new chiral diphosphine ligands could be employed as a ligand for the rhodium-catalyzed asymmetric catalyses. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/21186789/Asymmetric_synthesis_of_axially_chiral_biaryl_diphosphine_ligands_by_rhodium_catalyzed_enantioselective_intramolecular_double_[2_+_2_+_2]_cycloaddition_ L2 - https://doi.org/10.1021/ol102927y DB - PRIME DP - Unbound Medicine ER -