Tags

Type your tag names separated by a space and hit enter

Novel molecularly imprinted polymer using 1-(α-methyl acrylate)-3-methylimidazolium bromide as functional monomer for simultaneous extraction and determination of water-soluble acid dyes in wastewater and soft drink by solid phase extraction and high performance liquid chromatography.
J Chromatogr A. 2011 Feb 25; 1218(8):1115-21.JC

Abstract

Novel water-compatible molecularly imprinted polymers were synthesized in methanol-water systems with Tratarzine as template and 1-(α-methyl acrylate)-3-methylimidazolium bromide (1-MA-3MI-Br) as functional monomer, which has π-π hydrophobic, hydrogen-bonding and electrostatic interactions with template molecule. 1-MA-3MI-Br molecularly imprinted polymers (1-MA-3MI-Br-MIPs) were used as selective sorbents for the solid-phase extraction (SPE) of water-soluble acid dyes from wastewater and soft drink. The good linearity of the method was obtained in a range of 5.0-2000 μg/L with the correlation coefficient of > 0.999. The detection limits were in a range of 0.13-0.51 μg/L for the water-soluble acid dyes in wastewater and 0.095-0.84 μg/L for those in soft drink. The mean recoveries for the acid dyes are from 89.1% to 101.0% in spiked wastewater and 91.0-101.3% in spiked soft drink. Compared with strongly anion exchange solid phase extraction (SAX-SPE), mixture anion exchange solid phase extraction (MAX-SPE), and 1-MA-3MI-Br non-imprinted solid phase extraction (1-MA-3MI-Br-NISPE), almost all of the matrix interferences were removed by 1-MA-3MI-Br-MISPE, exhibiting higher selectivity, recovery and enrichment ability for the acid dyes and better baselines in the results of HPLC analysis.

Authors+Show Affiliations

College of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, PR China.No affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

21251659

Citation

Luo, Xubiao, et al. "Novel Molecularly Imprinted Polymer Using 1-(α-methyl Acrylate)-3-methylimidazolium Bromide as Functional Monomer for Simultaneous Extraction and Determination of Water-soluble Acid Dyes in Wastewater and Soft Drink By Solid Phase Extraction and High Performance Liquid Chromatography." Journal of Chromatography. A, vol. 1218, no. 8, 2011, pp. 1115-21.
Luo X, Zhan Y, Tu X, et al. Novel molecularly imprinted polymer using 1-(α-methyl acrylate)-3-methylimidazolium bromide as functional monomer for simultaneous extraction and determination of water-soluble acid dyes in wastewater and soft drink by solid phase extraction and high performance liquid chromatography. J Chromatogr A. 2011;1218(8):1115-21.
Luo, X., Zhan, Y., Tu, X., Huang, Y., Luo, S., & Yan, L. (2011). Novel molecularly imprinted polymer using 1-(α-methyl acrylate)-3-methylimidazolium bromide as functional monomer for simultaneous extraction and determination of water-soluble acid dyes in wastewater and soft drink by solid phase extraction and high performance liquid chromatography. Journal of Chromatography. A, 1218(8), 1115-21. https://doi.org/10.1016/j.chroma.2010.12.081
Luo X, et al. Novel Molecularly Imprinted Polymer Using 1-(α-methyl Acrylate)-3-methylimidazolium Bromide as Functional Monomer for Simultaneous Extraction and Determination of Water-soluble Acid Dyes in Wastewater and Soft Drink By Solid Phase Extraction and High Performance Liquid Chromatography. J Chromatogr A. 2011 Feb 25;1218(8):1115-21. PubMed PMID: 21251659.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Novel molecularly imprinted polymer using 1-(α-methyl acrylate)-3-methylimidazolium bromide as functional monomer for simultaneous extraction and determination of water-soluble acid dyes in wastewater and soft drink by solid phase extraction and high performance liquid chromatography. AU - Luo,Xubiao, AU - Zhan,Youcai, AU - Tu,Xinman, AU - Huang,Yining, AU - Luo,Shenglian, AU - Yan,Liushui, Y1 - 2010/12/28/ PY - 2010/10/03/received PY - 2010/12/16/revised PY - 2010/12/18/accepted PY - 2011/1/22/entrez PY - 2011/1/22/pubmed PY - 2011/5/11/medline SP - 1115 EP - 21 JF - Journal of chromatography. A JO - J Chromatogr A VL - 1218 IS - 8 N2 - Novel water-compatible molecularly imprinted polymers were synthesized in methanol-water systems with Tratarzine as template and 1-(α-methyl acrylate)-3-methylimidazolium bromide (1-MA-3MI-Br) as functional monomer, which has π-π hydrophobic, hydrogen-bonding and electrostatic interactions with template molecule. 1-MA-3MI-Br molecularly imprinted polymers (1-MA-3MI-Br-MIPs) were used as selective sorbents for the solid-phase extraction (SPE) of water-soluble acid dyes from wastewater and soft drink. The good linearity of the method was obtained in a range of 5.0-2000 μg/L with the correlation coefficient of > 0.999. The detection limits were in a range of 0.13-0.51 μg/L for the water-soluble acid dyes in wastewater and 0.095-0.84 μg/L for those in soft drink. The mean recoveries for the acid dyes are from 89.1% to 101.0% in spiked wastewater and 91.0-101.3% in spiked soft drink. Compared with strongly anion exchange solid phase extraction (SAX-SPE), mixture anion exchange solid phase extraction (MAX-SPE), and 1-MA-3MI-Br non-imprinted solid phase extraction (1-MA-3MI-Br-NISPE), almost all of the matrix interferences were removed by 1-MA-3MI-Br-MISPE, exhibiting higher selectivity, recovery and enrichment ability for the acid dyes and better baselines in the results of HPLC analysis. SN - 1873-3778 UR - https://www.unboundmedicine.com/medline/citation/21251659/Novel_molecularly_imprinted_polymer_using_1__α_methyl_acrylate__3_methylimidazolium_bromide_as_functional_monomer_for_simultaneous_extraction_and_determination_of_water_soluble_acid_dyes_in_wastewater_and_soft_drink_by_solid_phase_extraction_and_high_performance_liquid_chromatography_ L2 - https://linkinghub.elsevier.com/retrieve/pii/S0021-9673(10)01792-9 DB - PRIME DP - Unbound Medicine ER -