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Diverse strategies toward indenol and fulvene derivatives: Rh-catalyzed C-H activation of aryl ketones followed by coupling with internal alkynes.
J Am Chem Soc. 2011 Feb 23; 133(7):2154-6.JA

Abstract

The synthesis of indenols and fulvenes was achieved through Rh-catalyzed C-H bond activation of simple and diverse aryl ketone derivatives and subsequent coupling with internal alkynes. The process was found to involve either an α or γ dehydration step, depending on the substrate disposition and representing diverse pathways toward functionalized fulvenes.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Patureau FW
Organisch-Chemisches Institut der Westfälischen Wilhelms-Universität Münster, Corrensstrasse 40, 48149 Münster, Germany.
Besset T
No affiliation info available
Kuhl N
No affiliation info available
Glorius F
No affiliation info available

MeSH

AlkynesCatalysisCyclopentanesIndenesKetonesMolecular StructureRhodium

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

21265571

Citation

Patureau, Frederic W., et al. "Diverse Strategies Toward Indenol and Fulvene Derivatives: Rh-catalyzed C-H Activation of Aryl Ketones Followed By Coupling With Internal Alkynes." Journal of the American Chemical Society, vol. 133, no. 7, 2011, pp. 2154-6.
Patureau FW, Besset T, Kuhl N, et al. Diverse strategies toward indenol and fulvene derivatives: Rh-catalyzed C-H activation of aryl ketones followed by coupling with internal alkynes. J Am Chem Soc. 2011;133(7):2154-6.
Patureau, F. W., Besset, T., Kuhl, N., & Glorius, F. (2011). Diverse strategies toward indenol and fulvene derivatives: Rh-catalyzed C-H activation of aryl ketones followed by coupling with internal alkynes. Journal of the American Chemical Society, 133(7), 2154-6. https://doi.org/10.1021/ja110650m
Patureau FW, et al. Diverse Strategies Toward Indenol and Fulvene Derivatives: Rh-catalyzed C-H Activation of Aryl Ketones Followed By Coupling With Internal Alkynes. J Am Chem Soc. 2011 Feb 23;133(7):2154-6. PubMed PMID: 21265571.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Diverse strategies toward indenol and fulvene derivatives: Rh-catalyzed C-H activation of aryl ketones followed by coupling with internal alkynes. AU - Patureau,Frederic W, AU - Besset,Tatiana, AU - Kuhl,Nadine, AU - Glorius,Frank, Y1 - 2011/01/25/ PY - 2011/1/27/entrez PY - 2011/1/27/pubmed PY - 2011/5/17/medline SP - 2154 EP - 6 JF - Journal of the American Chemical Society JO - J Am Chem Soc VL - 133 IS - 7 N2 - The synthesis of indenols and fulvenes was achieved through Rh-catalyzed C-H bond activation of simple and diverse aryl ketone derivatives and subsequent coupling with internal alkynes. The process was found to involve either an α or γ dehydration step, depending on the substrate disposition and representing diverse pathways toward functionalized fulvenes. SN - 1520-5126 UR - https://www.unboundmedicine.com/medline/citation/21265571/Diverse_strategies_toward_indenol_and_fulvene_derivatives:_Rh_catalyzed_C_H_activation_of_aryl_ketones_followed_by_coupling_with_internal_alkynes_ DB - PRIME DP - Unbound Medicine ER -