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α,β-Divinyl tetrahydropyrroles as chiral chain diene ligands in rhodium(I)-catalyzed enantioselective conjugated additions.
Org Lett. 2011 Mar 04; 13(5):1122-5.OL

Abstract

A series of α,β-divinyl tetrahydropyrroles, synthesized by asymmetric allylic C-H bond activation/conjugated diene addition reaction of ene-2-dienes, were found to be very efficient chiral chain diene ligands in the rhodium-catalyzed conjugated addition of organoboronic acids to various α,β-unsaturated compounds, achieving the desired chiral adducts with good to excellent yields and ee values.

Authors+Show Affiliations

Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering, College of Chemistry, Peking University, Beijing, China.No affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

21309526

Citation

Li, Qian, et al. "Α,β-Divinyl Tetrahydropyrroles as Chiral Chain Diene Ligands in rhodium(I)-catalyzed Enantioselective Conjugated Additions." Organic Letters, vol. 13, no. 5, 2011, pp. 1122-5.
Li Q, Dong Z, Yu ZX. Α,β-Divinyl tetrahydropyrroles as chiral chain diene ligands in rhodium(I)-catalyzed enantioselective conjugated additions. Org Lett. 2011;13(5):1122-5.
Li, Q., Dong, Z., & Yu, Z. X. (2011). Α,β-Divinyl tetrahydropyrroles as chiral chain diene ligands in rhodium(I)-catalyzed enantioselective conjugated additions. Organic Letters, 13(5), 1122-5. https://doi.org/10.1021/ol103152t
Li Q, Dong Z, Yu ZX. Α,β-Divinyl Tetrahydropyrroles as Chiral Chain Diene Ligands in rhodium(I)-catalyzed Enantioselective Conjugated Additions. Org Lett. 2011 Mar 4;13(5):1122-5. PubMed PMID: 21309526.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - α,β-Divinyl tetrahydropyrroles as chiral chain diene ligands in rhodium(I)-catalyzed enantioselective conjugated additions. AU - Li,Qian, AU - Dong,Zhe, AU - Yu,Zhi-Xiang, Y1 - 2011/02/10/ PY - 2011/2/12/entrez PY - 2011/2/12/pubmed PY - 2011/5/7/medline SP - 1122 EP - 5 JF - Organic letters JO - Org Lett VL - 13 IS - 5 N2 - A series of α,β-divinyl tetrahydropyrroles, synthesized by asymmetric allylic C-H bond activation/conjugated diene addition reaction of ene-2-dienes, were found to be very efficient chiral chain diene ligands in the rhodium-catalyzed conjugated addition of organoboronic acids to various α,β-unsaturated compounds, achieving the desired chiral adducts with good to excellent yields and ee values. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/21309526/αβ_Divinyl_tetrahydropyrroles_as_chiral_chain_diene_ligands_in_rhodium_I__catalyzed_enantioselective_conjugated_additions_ L2 - https://doi.org/10.1021/ol103152t DB - PRIME DP - Unbound Medicine ER -