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Some important combinations of detection techniques for electrophoresis in capillaries and on chips with emphasis on electrochemical principles.
Electrophoresis. 2011 Apr; 32(8):795-810.E

Abstract

Analyses of very complex samples involving capillary and chip electrophoresis often require dual (multiple) detection to attain sufficient selectivity of determination. The present work reviews and critically evaluates selected combinations of electrochemical detection techniques among themselves and with absorption spectrometric, fluorescence and luminescence techniques. Amperometry, contact and contactless conductometry, UV photometry and fluorescence measurements are paid special attention. Some information is also given on combinations of spectrometric techniques with mass spectrometry. The properties of the detection systems are critically discussed, examples are illustrated in figures and some details on the characteristics of dual detectors and their applications are tabulated.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Opekar F
Charles University in Prague, Faculty of Science, Department of Analytical Chemistry, Prague, Czech Republic. opekar@natur.cuni.cz
Stulík K
No affiliation info available

MeSH

Electrophoresis, CapillaryElectrophoresis, MicrochipMass SpectrometryOrganic Chemicals

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't
Review

Language

eng

PubMed ID

21374631

Citation

Opekar, František, and Karel Stulík. "Some Important Combinations of Detection Techniques for Electrophoresis in Capillaries and On Chips With Emphasis On Electrochemical Principles." Electrophoresis, vol. 32, no. 8, 2011, pp. 795-810.
Opekar F, Stulík K. Some important combinations of detection techniques for electrophoresis in capillaries and on chips with emphasis on electrochemical principles. Electrophoresis. 2011;32(8):795-810.
Opekar, F., & Stulík, K. (2011). Some important combinations of detection techniques for electrophoresis in capillaries and on chips with emphasis on electrochemical principles. Electrophoresis, 32(8), 795-810. https://doi.org/10.1002/elps.201000455
Opekar F, Stulík K. Some Important Combinations of Detection Techniques for Electrophoresis in Capillaries and On Chips With Emphasis On Electrochemical Principles. Electrophoresis. 2011;32(8):795-810. PubMed PMID: 21374631.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Some important combinations of detection techniques for electrophoresis in capillaries and on chips with emphasis on electrochemical principles. AU - Opekar,František, AU - Stulík,Karel, Y1 - 2011/03/04/ PY - 2010/09/09/received PY - 2010/10/01/revised PY - 2010/10/07/accepted PY - 2011/3/5/entrez PY - 2011/3/5/pubmed PY - 2011/7/19/medline SP - 795 EP - 810 JF - Electrophoresis JO - Electrophoresis VL - 32 IS - 8 N2 - Analyses of very complex samples involving capillary and chip electrophoresis often require dual (multiple) detection to attain sufficient selectivity of determination. The present work reviews and critically evaluates selected combinations of electrochemical detection techniques among themselves and with absorption spectrometric, fluorescence and luminescence techniques. Amperometry, contact and contactless conductometry, UV photometry and fluorescence measurements are paid special attention. Some information is also given on combinations of spectrometric techniques with mass spectrometry. The properties of the detection systems are critically discussed, examples are illustrated in figures and some details on the characteristics of dual detectors and their applications are tabulated. SN - 1522-2683 UR - https://www.unboundmedicine.com/medline/citation/21374631/Some_important_combinations_of_detection_techniques_for_electrophoresis_in_capillaries_and_on_chips_with_emphasis_on_electrochemical_principles_ L2 - https://doi.org/10.1002/elps.201000455 DB - PRIME DP - Unbound Medicine ER -