Glucosamine-based primary amines as organocatalysts for the asymmetric aldol reaction.
J Org Chem. 2011 May 06; 76(9):3502-5.JO

Abstract

Glucosamine derivatives have been synthesized starting from commercially available N-acetyl-D-glucosamine/glucosamine hydrochloride and have been employed successfully as efficient organocatalysts for the direct asymmetric aldol reaction between cyclohexanone and aryl aldehydes having diversified substituents. Furthermore, the anomeric effect of various groups present at the anomeric position on the catalytic activity of these organocatalysts was also studied.

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Authors+Show Affiliations

Agarwal J

Department of Chemistry, Indian Institute of Technology, Roorkee 247 667, Uttarakhand, India.

Peddinti RK

No affiliation info available

MeSH

AldehydesAminesCatalysisGlucosamineKetonesStereoisomerism

Pub Type(s)

Journal Article

Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

21417422

Citation

Agarwal, Jyoti, and Rama Krishna Peddinti. "Glucosamine-based Primary Amines as Organocatalysts for the Asymmetric Aldol Reaction." The Journal of Organic Chemistry, vol. 76, no. 9, 2011, pp. 3502-5.

Agarwal J, Peddinti RK. Glucosamine-based primary amines as organocatalysts for the asymmetric aldol reaction. J Org Chem. 2011;76(9):3502-5.

Agarwal, J., & Peddinti, R. K. (2011). Glucosamine-based primary amines as organocatalysts for the asymmetric aldol reaction. The Journal of Organic Chemistry, 76(9), 3502-5. https://doi.org/10.1021/jo1023156

Agarwal J, Peddinti RK. Glucosamine-based Primary Amines as Organocatalysts for the Asymmetric Aldol Reaction. J Org Chem. 2011 May 6;76(9):3502-5. PubMed PMID: 21417422.

* Article titles in AMA citation format should be in sentence-case

TY - JOUR T1 - Glucosamine-based primary amines as organocatalysts for the asymmetric aldol reaction. AU - Agarwal,Jyoti, AU - Peddinti,Rama Krishna, Y1 - 2011/03/21/ PY - 2011/3/23/entrez PY - 2011/3/23/pubmed PY - 2011/8/19/medline SP - 3502 EP - 5 JF - The Journal of organic chemistry JO - J Org Chem VL - 76 IS - 9 N2 - Glucosamine derivatives have been synthesized starting from commercially available N-acetyl-D-glucosamine/glucosamine hydrochloride and have been employed successfully as efficient organocatalysts for the direct asymmetric aldol reaction between cyclohexanone and aryl aldehydes having diversified substituents. Furthermore, the anomeric effect of various groups present at the anomeric position on the catalytic activity of these organocatalysts was also studied. SN - 1520-6904 UR - https://www.unboundmedicine.com/medline/citation/21417422/Glucosamine_based_primary_amines_as_organocatalysts_for_the_asymmetric_aldol_reaction_ L2 - https://doi.org/10.1021/jo1023156 DB - PRIME DP - Unbound Medicine ER -

Tags

Glucosamine-based primary amines as organocatalysts for the asymmetric aldol reaction.J Org Chem. 2011 May 06; 76(9):3502-5.JO