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Silver triflate catalyzed reaction of 2-alkynylbenzaldoxime with aryne.
Org Lett. 2011 May 20; 13(10):2552-5.OL

Abstract

A novel and unexpected reaction of 2-alkynylbenzaldoxime with aryne in the presence of silver triflate (10 mol %) under mild conditions is discovered. This reaction proceeds through 6-endo-cyclization, [3 + 2] cycloaddition, and rearrangement, leading to 2-oxa-6-aza-bicyclo[3.2.2]nona-6,8-diene derivatives in moderate to good yields.

Authors+Show Affiliations

Department of Chemistry, Fudan University, Shanghai, China.No affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

21456516

Citation

Ren, Hui, et al. "Silver Triflate Catalyzed Reaction of 2-alkynylbenzaldoxime With Aryne." Organic Letters, vol. 13, no. 10, 2011, pp. 2552-5.
Ren H, Luo Y, Ye S, et al. Silver triflate catalyzed reaction of 2-alkynylbenzaldoxime with aryne. Org Lett. 2011;13(10):2552-5.
Ren, H., Luo, Y., Ye, S., & Wu, J. (2011). Silver triflate catalyzed reaction of 2-alkynylbenzaldoxime with aryne. Organic Letters, 13(10), 2552-5. https://doi.org/10.1021/ol200629y
Ren H, et al. Silver Triflate Catalyzed Reaction of 2-alkynylbenzaldoxime With Aryne. Org Lett. 2011 May 20;13(10):2552-5. PubMed PMID: 21456516.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Silver triflate catalyzed reaction of 2-alkynylbenzaldoxime with aryne. AU - Ren,Hui, AU - Luo,Yong, AU - Ye,Shengqing, AU - Wu,Jie, Y1 - 2011/04/01/ PY - 2011/4/5/entrez PY - 2011/4/5/pubmed PY - 2011/7/27/medline SP - 2552 EP - 5 JF - Organic letters JO - Org Lett VL - 13 IS - 10 N2 - A novel and unexpected reaction of 2-alkynylbenzaldoxime with aryne in the presence of silver triflate (10 mol %) under mild conditions is discovered. This reaction proceeds through 6-endo-cyclization, [3 + 2] cycloaddition, and rearrangement, leading to 2-oxa-6-aza-bicyclo[3.2.2]nona-6,8-diene derivatives in moderate to good yields. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/21456516/Silver_triflate_catalyzed_reaction_of_2_alkynylbenzaldoxime_with_aryne_ L2 - https://doi.org/10.1021/ol200629y DB - PRIME DP - Unbound Medicine ER -