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Rhodium-catalyzed oxidative ortho-acylation of benzamides with aldehydes: direct functionalization of the sp2 C-H bond.
Org Lett. 2011 Aug 19; 13(16):4390-3.OL

Abstract

A rhodium-catalyzed oxidative acylation of benzamides with aryl aldehydes via direct sp(2) C-H bond cleavage is described. In the presence of [Cp*RhCl(2)](2), AgSbF(6), and silver carbonate as an oxidant, N,N-diethyl benzamides can be effectively carbonylated to yield ortho-acyl benzamides.

Authors+Show Affiliations

Department of Chemistry, University of Ulsan, Ulsan, 680-749, Republic of Korea.No affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

21793534

Citation

Park, Jihye, et al. "Rhodium-catalyzed Oxidative Ortho-acylation of Benzamides With Aldehydes: Direct Functionalization of the Sp2 C-H Bond." Organic Letters, vol. 13, no. 16, 2011, pp. 4390-3.
Park J, Park E, Kim A, et al. Rhodium-catalyzed oxidative ortho-acylation of benzamides with aldehydes: direct functionalization of the sp2 C-H bond. Org Lett. 2011;13(16):4390-3.
Park, J., Park, E., Kim, A., Lee, Y., Chi, K. W., Kwak, J. H., Jung, Y. H., & Kim, I. S. (2011). Rhodium-catalyzed oxidative ortho-acylation of benzamides with aldehydes: direct functionalization of the sp2 C-H bond. Organic Letters, 13(16), 4390-3. https://doi.org/10.1021/ol201729w
Park J, et al. Rhodium-catalyzed Oxidative Ortho-acylation of Benzamides With Aldehydes: Direct Functionalization of the Sp2 C-H Bond. Org Lett. 2011 Aug 19;13(16):4390-3. PubMed PMID: 21793534.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Rhodium-catalyzed oxidative ortho-acylation of benzamides with aldehydes: direct functionalization of the sp2 C-H bond. AU - Park,Jihye, AU - Park,Eonjeong, AU - Kim,Aejin, AU - Lee,Youngil, AU - Chi,Ki-Whan, AU - Kwak,Jong Hwan, AU - Jung,Young Hoon, AU - Kim,In Su, Y1 - 2011/07/27/ PY - 2011/7/29/entrez PY - 2011/7/29/pubmed PY - 2011/12/13/medline SP - 4390 EP - 3 JF - Organic letters JO - Org Lett VL - 13 IS - 16 N2 - A rhodium-catalyzed oxidative acylation of benzamides with aryl aldehydes via direct sp(2) C-H bond cleavage is described. In the presence of [Cp*RhCl(2)](2), AgSbF(6), and silver carbonate as an oxidant, N,N-diethyl benzamides can be effectively carbonylated to yield ortho-acyl benzamides. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/21793534/Rhodium_catalyzed_oxidative_ortho_acylation_of_benzamides_with_aldehydes:_direct_functionalization_of_the_sp2_C_H_bond_ L2 - https://doi.org/10.1021/ol201729w DB - PRIME DP - Unbound Medicine ER -