Preparation and evaluation of molecularly imprinted ionic liquids polymer as sorbent for on-line solid-phase extraction of chlorsulfuron in environmental water samples.J Chromatogr A. 2011 Sep 16; 1218(37):6271-7.JC
Abstract
In this report, vinylimidazolium ionic liquid as a functional monomer for preparation of chlorsulfuron (CS) imprinted polymers were first studied. The imprinted materials showed high selectivity for CS, and fast kinetics so that adsorption equilibrium was achieved within 5 min. These materials have been further employed to detect trace CS from water samples by online preconcentration coupled with HPLC. The sorbent offered good linearity (0.005-30 μg L(-1), r(2)>0.99) for on-line solid-phase extraction of trace chlorsulfuron. Under the optimal experimental conditions, the recovery for chlorsulfuron was in the range of 81.0-110.1% for the water samples, with RSDs ranging from 1.2 to 7.6%.
Links
MeSH
AdsorptionChromatography, High Pressure LiquidHydrogen-Ion ConcentrationImidazolesIonic LiquidsKineticsMicroscopy, Electron, ScanningMolecular ImprintingReproducibility of ResultsSensitivity and SpecificitySolid Phase ExtractionSpectroscopy, Fourier Transform InfraredSulfonamidesTriazinesVinyl CompoundsWater Pollutants, Chemical
Pub Type(s)
Journal Article
Research Support, Non-U.S. Gov't
Language
eng
PubMed ID
21807367
Citation
Guo, Lu, et al. "Preparation and Evaluation of Molecularly Imprinted Ionic Liquids Polymer as Sorbent for On-line Solid-phase Extraction of Chlorsulfuron in Environmental Water Samples." Journal of Chromatography. A, vol. 1218, no. 37, 2011, pp. 6271-7.
Guo L, Deng Q, Fang G, et al. Preparation and evaluation of molecularly imprinted ionic liquids polymer as sorbent for on-line solid-phase extraction of chlorsulfuron in environmental water samples. J Chromatogr A. 2011;1218(37):6271-7.
Guo, L., Deng, Q., Fang, G., Gao, W., & Wang, S. (2011). Preparation and evaluation of molecularly imprinted ionic liquids polymer as sorbent for on-line solid-phase extraction of chlorsulfuron in environmental water samples. Journal of Chromatography. A, 1218(37), 6271-7. https://doi.org/10.1016/j.chroma.2011.07.016
Guo L, et al. Preparation and Evaluation of Molecularly Imprinted Ionic Liquids Polymer as Sorbent for On-line Solid-phase Extraction of Chlorsulfuron in Environmental Water Samples. J Chromatogr A. 2011 Sep 16;1218(37):6271-7. PubMed PMID: 21807367.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR
T1 - Preparation and evaluation of molecularly imprinted ionic liquids polymer as sorbent for on-line solid-phase extraction of chlorsulfuron in environmental water samples.
AU - Guo,Lu,
AU - Deng,Qiliang,
AU - Fang,Guozhen,
AU - Gao,Wei,
AU - Wang,Shuo,
Y1 - 2011/07/20/
PY - 2010/12/31/received
PY - 2011/06/20/revised
PY - 2011/07/08/accepted
PY - 2011/8/3/entrez
PY - 2011/8/3/pubmed
PY - 2011/10/25/medline
SP - 6271
EP - 7
JF - Journal of chromatography. A
JO - J Chromatogr A
VL - 1218
IS - 37
N2 - In this report, vinylimidazolium ionic liquid as a functional monomer for preparation of chlorsulfuron (CS) imprinted polymers were first studied. The imprinted materials showed high selectivity for CS, and fast kinetics so that adsorption equilibrium was achieved within 5 min. These materials have been further employed to detect trace CS from water samples by online preconcentration coupled with HPLC. The sorbent offered good linearity (0.005-30 μg L(-1), r(2)>0.99) for on-line solid-phase extraction of trace chlorsulfuron. Under the optimal experimental conditions, the recovery for chlorsulfuron was in the range of 81.0-110.1% for the water samples, with RSDs ranging from 1.2 to 7.6%.
SN - 1873-3778
UR - https://www.unboundmedicine.com/medline/citation/21807367/Preparation_and_evaluation_of_molecularly_imprinted_ionic_liquids_polymer_as_sorbent_for_on_line_solid_phase_extraction_of_chlorsulfuron_in_environmental_water_samples_
L2 - https://linkinghub.elsevier.com/retrieve/pii/S0021-9673(11)01006-5
DB - PRIME
DP - Unbound Medicine
ER -