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Regio- and stereoselective synthesis of 2-deoxy-C-aryl glycosides via palladium catalyzed decarboxylative reactions.
Org Lett. 2011 Sep 02; 13(17):4608-11.OL

Abstract

An efficient and versatile approach for the synthesis of 2-deoxy-C-aryl glycosides is reported. This strategy is based on a palladium-catalyzed decarboxylative Heck coupling reaction of benzoic acids and glycals. A wide variety of glycals and benzoic acids have been screened, and all these reactions could afford the desired C-aryl glycoside products in moderate to good yields with exclusive regio- and stereoselectivities.

Authors+Show Affiliations

Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore.No affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

21815638

Citation

Xiang, Shaohua, et al. "Regio- and Stereoselective Synthesis of 2-deoxy-C-aryl Glycosides Via Palladium Catalyzed Decarboxylative Reactions." Organic Letters, vol. 13, no. 17, 2011, pp. 4608-11.
Xiang S, Cai S, Zeng J, et al. Regio- and stereoselective synthesis of 2-deoxy-C-aryl glycosides via palladium catalyzed decarboxylative reactions. Org Lett. 2011;13(17):4608-11.
Xiang, S., Cai, S., Zeng, J., & Liu, X. W. (2011). Regio- and stereoselective synthesis of 2-deoxy-C-aryl glycosides via palladium catalyzed decarboxylative reactions. Organic Letters, 13(17), 4608-11. https://doi.org/10.1021/ol201820m
Xiang S, et al. Regio- and Stereoselective Synthesis of 2-deoxy-C-aryl Glycosides Via Palladium Catalyzed Decarboxylative Reactions. Org Lett. 2011 Sep 2;13(17):4608-11. PubMed PMID: 21815638.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Regio- and stereoselective synthesis of 2-deoxy-C-aryl glycosides via palladium catalyzed decarboxylative reactions. AU - Xiang,Shaohua, AU - Cai,Shuting, AU - Zeng,Jing, AU - Liu,Xue-Wei, Y1 - 2011/08/04/ PY - 2011/8/6/entrez PY - 2011/8/6/pubmed PY - 2011/12/13/medline SP - 4608 EP - 11 JF - Organic letters JO - Org. Lett. VL - 13 IS - 17 N2 - An efficient and versatile approach for the synthesis of 2-deoxy-C-aryl glycosides is reported. This strategy is based on a palladium-catalyzed decarboxylative Heck coupling reaction of benzoic acids and glycals. A wide variety of glycals and benzoic acids have been screened, and all these reactions could afford the desired C-aryl glycoside products in moderate to good yields with exclusive regio- and stereoselectivities. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/21815638/Regio__and_stereoselective_synthesis_of_2_deoxy_C_aryl_glycosides_via_palladium_catalyzed_decarboxylative_reactions_ L2 - https://dx.doi.org/10.1021/ol201820m DB - PRIME DP - Unbound Medicine ER -