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Three triterpenoid saponins acylated with monoterpenic acid from Gymnocladus chinensis.
J Asian Nat Prod Res. 2011 Sep; 13(9):869-78.JA

Abstract

A new triterpenoid saponin acylated with monoterpenic acid, together with two known triterpenoid saponins, has been isolated from the fruit of Gymnocladus chinensis Baill. Their structures were elucidated as 2β,23-dihydroxy-3-O-α-L-rhamnopyranosyl-21-O-{(6S)-2-trans-2,6-dimethyl-6-O-[3-O-(β-D-glucopyranosyl)-4-O-((6S)-2-trans-2,6-dimethyl-6-hydroxy-2,7-octadienoyl)-β-L-arabinopyranosyl]-2,7-octadienoyl}-acacic acid 28-O-β-D-xylopyranosyl-(1 → 3)-β-D-xylopyranosyl-(1 → 4)-α-L-rhamnopyranosyl-(1 → 2)-[α-L-rhamnopyranosyl-(1 → 6)]-β-D-glucopyranosyl ester (1), gymnocladus saponin E (2), and gymnocladus saponin F(2) (3).

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Authors+Show Affiliations

Wen Q
State Key Laboratory of Natural and Biomimetic Drugs, School of Pharmaceutical Science, Peking University, Beijng 100191, China.
Yuan D
No affiliation info available
Xie KH
No affiliation info available
Cai TZ
No affiliation info available
Fu HZ
No affiliation info available

MeSH

Carbohydrate SequenceDrugs, Chinese HerbalFabaceaeFruitMolecular StructureMonoterpenesNuclear Magnetic Resonance, BiomolecularSaponinsStereoisomerismTriterpenes

Pub Type(s)

Journal Article

Language

eng

PubMed ID

21830893

Citation

Wen, Qi, et al. "Three Triterpenoid Saponins Acylated With Monoterpenic Acid From Gymnocladus Chinensis." Journal of Asian Natural Products Research, vol. 13, no. 9, 2011, pp. 869-78.
Wen Q, Yuan D, Xie KH, et al. Three triterpenoid saponins acylated with monoterpenic acid from Gymnocladus chinensis. J Asian Nat Prod Res. 2011;13(9):869-78.
Wen, Q., Yuan, D., Xie, K. H., Cai, T. Z., & Fu, H. Z. (2011). Three triterpenoid saponins acylated with monoterpenic acid from Gymnocladus chinensis. Journal of Asian Natural Products Research, 13(9), 869-78. https://doi.org/10.1080/10286020.2011.589839
Wen Q, et al. Three Triterpenoid Saponins Acylated With Monoterpenic Acid From Gymnocladus Chinensis. J Asian Nat Prod Res. 2011;13(9):869-78. PubMed PMID: 21830893.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Three triterpenoid saponins acylated with monoterpenic acid from Gymnocladus chinensis. AU - Wen,Qi, AU - Yuan,Dan, AU - Xie,Ke-Hui, AU - Cai,Tian-Zhi, AU - Fu,Hong-Zheng, PY - 2011/8/12/entrez PY - 2011/8/13/pubmed PY - 2011/10/26/medline SP - 869 EP - 78 JF - Journal of Asian natural products research JO - J Asian Nat Prod Res VL - 13 IS - 9 N2 - A new triterpenoid saponin acylated with monoterpenic acid, together with two known triterpenoid saponins, has been isolated from the fruit of Gymnocladus chinensis Baill. Their structures were elucidated as 2β,23-dihydroxy-3-O-α-L-rhamnopyranosyl-21-O-{(6S)-2-trans-2,6-dimethyl-6-O-[3-O-(β-D-glucopyranosyl)-4-O-((6S)-2-trans-2,6-dimethyl-6-hydroxy-2,7-octadienoyl)-β-L-arabinopyranosyl]-2,7-octadienoyl}-acacic acid 28-O-β-D-xylopyranosyl-(1 → 3)-β-D-xylopyranosyl-(1 → 4)-α-L-rhamnopyranosyl-(1 → 2)-[α-L-rhamnopyranosyl-(1 → 6)]-β-D-glucopyranosyl ester (1), gymnocladus saponin E (2), and gymnocladus saponin F(2) (3). SN - 1477-2213 UR - https://www.unboundmedicine.com/medline/citation/21830893/Three_triterpenoid_saponins_acylated_with_monoterpenic_acid_from_Gymnocladus_chinensis_ L2 - https://www.tandfonline.com/doi/full/10.1080/10286020.2011.589839 DB - PRIME DP - Unbound Medicine ER -