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A new type of bis(sulfonamide)-diamine ligand for a Cu(OTf)2-catalyzed asymmetric Friedel-Crafts alkylation reaction of indoles with nitroalkenes.
Org Lett. 2011 Sep 16; 13(18):4834-7.OL

Abstract

Chiral bis(sulfonamide)-diamine served as new type of ligand for a Cu(OTf)(2)-catalyzed asymmetric Friedel-Crafts alkylation reaction of indoles with nitroalkenes. The desired products were obtained with up to 99% yield and 97% ee.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Wu J
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, China.
Li X
No affiliation info available
Wu F
No affiliation info available
Wan B
No affiliation info available

MeSH

AlkenesAlkylationCatalysisCopperDiaminesIndolesLigandsMesylatesModels, MolecularMolecular ConformationNitro CompoundsOrganometallic CompoundsQuantum TheoryStereoisomerismSulfonamides

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

21861451

Citation

Wu, Jing, et al. "A New Type of Bis(sulfonamide)-diamine Ligand for a Cu(OTf)2-catalyzed Asymmetric Friedel-Crafts Alkylation Reaction of Indoles With Nitroalkenes." Organic Letters, vol. 13, no. 18, 2011, pp. 4834-7.
Wu J, Li X, Wu F, et al. A new type of bis(sulfonamide)-diamine ligand for a Cu(OTf)2-catalyzed asymmetric Friedel-Crafts alkylation reaction of indoles with nitroalkenes. Org Lett. 2011;13(18):4834-7.
Wu, J., Li, X., Wu, F., & Wan, B. (2011). A new type of bis(sulfonamide)-diamine ligand for a Cu(OTf)2-catalyzed asymmetric Friedel-Crafts alkylation reaction of indoles with nitroalkenes. Organic Letters, 13(18), 4834-7. https://doi.org/10.1021/ol201914r
Wu J, et al. A New Type of Bis(sulfonamide)-diamine Ligand for a Cu(OTf)2-catalyzed Asymmetric Friedel-Crafts Alkylation Reaction of Indoles With Nitroalkenes. Org Lett. 2011 Sep 16;13(18):4834-7. PubMed PMID: 21861451.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - A new type of bis(sulfonamide)-diamine ligand for a Cu(OTf)2-catalyzed asymmetric Friedel-Crafts alkylation reaction of indoles with nitroalkenes. AU - Wu,Jing, AU - Li,Xincheng, AU - Wu,Fan, AU - Wan,Boshun, Y1 - 2011/08/23/ PY - 2011/8/25/entrez PY - 2011/8/25/pubmed PY - 2011/12/13/medline SP - 4834 EP - 7 JF - Organic letters JO - Org Lett VL - 13 IS - 18 N2 - Chiral bis(sulfonamide)-diamine served as new type of ligand for a Cu(OTf)(2)-catalyzed asymmetric Friedel-Crafts alkylation reaction of indoles with nitroalkenes. The desired products were obtained with up to 99% yield and 97% ee. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/21861451/A_new_type_of_bis_sulfonamide__diamine_ligand_for_a_Cu_OTf_2_catalyzed_asymmetric_Friedel_Crafts_alkylation_reaction_of_indoles_with_nitroalkenes_ L2 - https://doi.org/10.1021/ol201914r DB - PRIME DP - Unbound Medicine ER -