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Rhodium-catalyzed olefin isomerization/enantioselective intramolecular Alder-ene reaction cascade.
Org Lett. 2011 Sep 16; 13(18):4894-7.OL

Abstract

The olefin isomerization/enantioselective intramolecular Alder-ene reaction cascade was achieved by using a cationic rhodium(I)/(R)-BINAP complex as a catalyst. A variety of substituted dihydrobenzofurans and dihydronaphthofurans were obtained from phenol- or naphthol-linked 1,7-enynes, respectively, with good yields and ee values.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Okamoto R
Department of Applied Chemistry, Graduate School of Engineering, and Instrumentation Analysis Center, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan.
Okazaki E
No affiliation info available
Noguchi K
No affiliation info available
Tanaka K
No affiliation info available

MeSH

AlkenesCatalysisFuransMolecular StructureOrganometallic CompoundsRhodiumStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

21866888

Citation

Okamoto, Ryuichi, et al. "Rhodium-catalyzed Olefin Isomerization/enantioselective Intramolecular Alder-ene Reaction Cascade." Organic Letters, vol. 13, no. 18, 2011, pp. 4894-7.
Okamoto R, Okazaki E, Noguchi K, et al. Rhodium-catalyzed olefin isomerization/enantioselective intramolecular Alder-ene reaction cascade. Org Lett. 2011;13(18):4894-7.
Okamoto, R., Okazaki, E., Noguchi, K., & Tanaka, K. (2011). Rhodium-catalyzed olefin isomerization/enantioselective intramolecular Alder-ene reaction cascade. Organic Letters, 13(18), 4894-7. https://doi.org/10.1021/ol201986e
Okamoto R, et al. Rhodium-catalyzed Olefin Isomerization/enantioselective Intramolecular Alder-ene Reaction Cascade. Org Lett. 2011 Sep 16;13(18):4894-7. PubMed PMID: 21866888.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Rhodium-catalyzed olefin isomerization/enantioselective intramolecular Alder-ene reaction cascade. AU - Okamoto,Ryuichi, AU - Okazaki,Eri, AU - Noguchi,Keiichi, AU - Tanaka,Ken, Y1 - 2011/08/25/ PY - 2011/8/27/entrez PY - 2011/8/27/pubmed PY - 2011/12/13/medline SP - 4894 EP - 7 JF - Organic letters JO - Org Lett VL - 13 IS - 18 N2 - The olefin isomerization/enantioselective intramolecular Alder-ene reaction cascade was achieved by using a cationic rhodium(I)/(R)-BINAP complex as a catalyst. A variety of substituted dihydrobenzofurans and dihydronaphthofurans were obtained from phenol- or naphthol-linked 1,7-enynes, respectively, with good yields and ee values. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/21866888/Rhodium_catalyzed_olefin_isomerization/enantioselective_intramolecular_Alder_ene_reaction_cascade_ DB - PRIME DP - Unbound Medicine ER -