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Palladium catalyzed stereoselective C-glycosylation of glycals with enol triflates.
Org Lett. 2011 Oct 21; 13(20):5648-51.OL

Abstract

An efficient palladium catalyzed C-glycosylation of glycals with enol triflates has been established. The coupling reactions took place on the anomeric carbon, and the coupling products gave exclusively α isomers. The flexibility of the reaction was exemplified by the broad spectra of substrate scope, constituted of glycals protected with good leaving groups as well as an assortment of enol triflates.

Authors+Show Affiliations

Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371.No affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

21954934

Citation

Bai, Yaguang, et al. "Palladium Catalyzed Stereoselective C-glycosylation of Glycals With Enol Triflates." Organic Letters, vol. 13, no. 20, 2011, pp. 5648-51.
Bai Y, Leow M, Zeng J, et al. Palladium catalyzed stereoselective C-glycosylation of glycals with enol triflates. Org Lett. 2011;13(20):5648-51.
Bai, Y., Leow, M., Zeng, J., & Liu, X. W. (2011). Palladium catalyzed stereoselective C-glycosylation of glycals with enol triflates. Organic Letters, 13(20), 5648-51. https://doi.org/10.1021/ol202368n
Bai Y, et al. Palladium Catalyzed Stereoselective C-glycosylation of Glycals With Enol Triflates. Org Lett. 2011 Oct 21;13(20):5648-51. PubMed PMID: 21954934.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Palladium catalyzed stereoselective C-glycosylation of glycals with enol triflates. AU - Bai,Yaguang, AU - Leow,Minli, AU - Zeng,Jing, AU - Liu,Xue-Wei, Y1 - 2011/09/28/ PY - 2011/9/30/entrez PY - 2011/10/1/pubmed PY - 2011/12/22/medline SP - 5648 EP - 51 JF - Organic letters JO - Org Lett VL - 13 IS - 20 N2 - An efficient palladium catalyzed C-glycosylation of glycals with enol triflates has been established. The coupling reactions took place on the anomeric carbon, and the coupling products gave exclusively α isomers. The flexibility of the reaction was exemplified by the broad spectra of substrate scope, constituted of glycals protected with good leaving groups as well as an assortment of enol triflates. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/21954934/Palladium_catalyzed_stereoselective_C_glycosylation_of_glycals_with_enol_triflates_ L2 - https://doi.org/10.1021/ol202368n DB - PRIME DP - Unbound Medicine ER -