Tags

Type your tag names separated by a space and hit enter

Palladium(0)-catalyzed cyclization of 1,6-diyn-3-yl carbonates with a nucleophilic functionality: efficient synthesis of polycyclic benzo[b]fluorene derivatives via allene intermediates.
Org Biomol Chem. 2012 May 14; 10(18):3696-704.OB

Abstract

We report in this paper an interesting tandem reaction involving sequential palladium(0)-catalyzed decarboxylation of diynylic carbonates, intramolecular nucleophilic cyclization and Schmittel reaction, which provides a facile method for the synthesis of a variety of polycyclic benzo[b]fluorene derivatives from easily accessible starting materials.

Links

Publisher Full Text (DOI)

Authors+Show Affiliations

Zhu S
Department of Chemistry, Zhejiang University, Hangzhou, PR China.
Wu L
No affiliation info available
Huang X
No affiliation info available

MeSH

CarbonatesCatalysisCyclizationFluorenesModels, MolecularMolecular StructureOrganometallic CompoundsPalladiumPolycyclic Aromatic HydrocarbonsStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

22495553

Citation

Zhu, Shugao, et al. "Palladium(0)-catalyzed Cyclization of 1,6-diyn-3-yl Carbonates With a Nucleophilic Functionality: Efficient Synthesis of Polycyclic Benzo[b]fluorene Derivatives Via Allene Intermediates." Organic & Biomolecular Chemistry, vol. 10, no. 18, 2012, pp. 3696-704.
Zhu S, Wu L, Huang X. Palladium(0)-catalyzed cyclization of 1,6-diyn-3-yl carbonates with a nucleophilic functionality: efficient synthesis of polycyclic benzo[b]fluorene derivatives via allene intermediates. Org Biomol Chem. 2012;10(18):3696-704.
Zhu, S., Wu, L., & Huang, X. (2012). Palladium(0)-catalyzed cyclization of 1,6-diyn-3-yl carbonates with a nucleophilic functionality: efficient synthesis of polycyclic benzo[b]fluorene derivatives via allene intermediates. Organic & Biomolecular Chemistry, 10(18), 3696-704. https://doi.org/10.1039/c2ob07148g
Zhu S, Wu L, Huang X. Palladium(0)-catalyzed Cyclization of 1,6-diyn-3-yl Carbonates With a Nucleophilic Functionality: Efficient Synthesis of Polycyclic Benzo[b]fluorene Derivatives Via Allene Intermediates. Org Biomol Chem. 2012 May 14;10(18):3696-704. PubMed PMID: 22495553.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Palladium(0)-catalyzed cyclization of 1,6-diyn-3-yl carbonates with a nucleophilic functionality: efficient synthesis of polycyclic benzo[b]fluorene derivatives via allene intermediates. AU - Zhu,Shugao, AU - Wu,Luling, AU - Huang,Xian, Y1 - 2012/04/03/ PY - 2012/4/13/entrez PY - 2012/4/13/pubmed PY - 2012/10/10/medline SP - 3696 EP - 704 JF - Organic & biomolecular chemistry JO - Org Biomol Chem VL - 10 IS - 18 N2 - We report in this paper an interesting tandem reaction involving sequential palladium(0)-catalyzed decarboxylation of diynylic carbonates, intramolecular nucleophilic cyclization and Schmittel reaction, which provides a facile method for the synthesis of a variety of polycyclic benzo[b]fluorene derivatives from easily accessible starting materials. SN - 1477-0539 UR - https://www.unboundmedicine.com/medline/citation/22495553/Palladium_0__catalyzed_cyclization_of_16_diyn_3_yl_carbonates_with_a_nucleophilic_functionality:_efficient_synthesis_of_polycyclic_benzo[b]fluorene_derivatives_via_allene_intermediates_ DB - PRIME DP - Unbound Medicine ER -