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D-Glucosamine in a chimeric prolinamide organocatalyst for direct asymmetric aldol addition.
Carbohydr Res. 2012 Jul 15; 356:273-7.CR

Abstract

O-TBDPS D-glucosamine coupled with l-proline is reported to act as an efficient organocatalyst in the accomplishment of direct aldol reactions. Excellent results, in terms of chemical yields, as well as diastereomeric and enantiomeric ratios, are reported for the catalyzed additions of cyclohexanone and acetone to variously substituted benzaldehydes.

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Authors+Show Affiliations

De Nisco M
Dipartimento di Scienze Chimiche, Università di Napoli Federico II, Napoli, Italy.
Pedatella S
No affiliation info available
Bektaş S
No affiliation info available
Nucci A
No affiliation info available
Caputo R
No affiliation info available

MeSH

AcetoneAldehydesBenzaldehydesCarbohydrate ConformationCatalysisCyclohexanonesGlucosamineHydrophobic and Hydrophilic InteractionsMagnetic Resonance SpectroscopyMolecular StructureProlineStereoisomerism

Pub Type(s)

Journal Article

Language

eng

PubMed ID

22575747

Citation

De Nisco, Mauro, et al. "D-Glucosamine in a Chimeric Prolinamide Organocatalyst for Direct Asymmetric Aldol Addition." Carbohydrate Research, vol. 356, 2012, pp. 273-7.
De Nisco M, Pedatella S, Bektaş S, et al. D-Glucosamine in a chimeric prolinamide organocatalyst for direct asymmetric aldol addition. Carbohydr Res. 2012;356:273-7.
De Nisco, M., Pedatella, S., Bektaş, S., Nucci, A., & Caputo, R. (2012). D-Glucosamine in a chimeric prolinamide organocatalyst for direct asymmetric aldol addition. Carbohydrate Research, 356, 273-7. https://doi.org/10.1016/j.carres.2012.03.041
De Nisco M, et al. D-Glucosamine in a Chimeric Prolinamide Organocatalyst for Direct Asymmetric Aldol Addition. Carbohydr Res. 2012 Jul 15;356:273-7. PubMed PMID: 22575747.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - D-Glucosamine in a chimeric prolinamide organocatalyst for direct asymmetric aldol addition. AU - De Nisco,Mauro, AU - Pedatella,Silvana, AU - Bektaş,Semiha, AU - Nucci,Ada, AU - Caputo,Romualdo, Y1 - 2012/04/18/ PY - 2012/01/29/received PY - 2012/03/28/revised PY - 2012/03/30/accepted PY - 2012/5/12/entrez PY - 2012/5/12/pubmed PY - 2012/11/14/medline SP - 273 EP - 7 JF - Carbohydrate research JO - Carbohydr Res VL - 356 N2 - O-TBDPS D-glucosamine coupled with l-proline is reported to act as an efficient organocatalyst in the accomplishment of direct aldol reactions. Excellent results, in terms of chemical yields, as well as diastereomeric and enantiomeric ratios, are reported for the catalyzed additions of cyclohexanone and acetone to variously substituted benzaldehydes. SN - 1873-426X UR - https://www.unboundmedicine.com/medline/citation/22575747/D_Glucosamine_in_a_chimeric_prolinamide_organocatalyst_for_direct_asymmetric_aldol_addition_ L2 - https://linkinghub.elsevier.com/retrieve/pii/S0008-6215(12)00149-8 DB - PRIME DP - Unbound Medicine ER -