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Rhodium(III)-catalyzed cyclization-olefination of N-acetoxyl ketoimine-alkynes.
Org Lett. 2012 Jul 06; 14(13):3400-3.OL

Abstract

N-Acetoxyl ketoimine-alkynes undergo Rh(III)-catalyzed oxidative olefination to afford (2-acetoxymethyl)isoquinolines bearing an ortho-olefinated aryl group via a sequence that involves (1) Rh(III)-catalyzed alkyne cyclization with intramolecular 1,3-acetoxyl migration and (2) isoquinoline-directed ortho C-H olefination.

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Authors+Show Affiliations

Zhao P
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China.
Wang F
No affiliation info available
Han K
No affiliation info available
Li X
No affiliation info available

MeSH

AlkenesAlkynesCatalysisCyclizationIminesMolecular StructureOrganometallic CompoundsRhodiumStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

22690947

Citation

Zhao, Peng, et al. "Rhodium(III)-catalyzed Cyclization-olefination of N-acetoxyl Ketoimine-alkynes." Organic Letters, vol. 14, no. 13, 2012, pp. 3400-3.
Zhao P, Wang F, Han K, et al. Rhodium(III)-catalyzed cyclization-olefination of N-acetoxyl ketoimine-alkynes. Org Lett. 2012;14(13):3400-3.
Zhao, P., Wang, F., Han, K., & Li, X. (2012). Rhodium(III)-catalyzed cyclization-olefination of N-acetoxyl ketoimine-alkynes. Organic Letters, 14(13), 3400-3. https://doi.org/10.1021/ol301371p
Zhao P, et al. Rhodium(III)-catalyzed Cyclization-olefination of N-acetoxyl Ketoimine-alkynes. Org Lett. 2012 Jul 6;14(13):3400-3. PubMed PMID: 22690947.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Rhodium(III)-catalyzed cyclization-olefination of N-acetoxyl ketoimine-alkynes. AU - Zhao,Peng, AU - Wang,Fen, AU - Han,Keli, AU - Li,Xingwei, Y1 - 2012/06/12/ PY - 2012/6/14/entrez PY - 2012/6/14/pubmed PY - 2012/11/8/medline SP - 3400 EP - 3 JF - Organic letters JO - Org Lett VL - 14 IS - 13 N2 - N-Acetoxyl ketoimine-alkynes undergo Rh(III)-catalyzed oxidative olefination to afford (2-acetoxymethyl)isoquinolines bearing an ortho-olefinated aryl group via a sequence that involves (1) Rh(III)-catalyzed alkyne cyclization with intramolecular 1,3-acetoxyl migration and (2) isoquinoline-directed ortho C-H olefination. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/22690947/Rhodium_III__catalyzed_cyclization_olefination_of_N_acetoxyl_ketoimine_alkynes_ L2 - https://doi.org/10.1021/ol301371p DB - PRIME DP - Unbound Medicine ER -