Rhodium(III)-catalyzed cyclization-olefination of N-acetoxyl ketoimine-alkynes.Org Lett. 2012 Jul 06; 14(13):3400-3.OL
Abstract
N-Acetoxyl ketoimine-alkynes undergo Rh(III)-catalyzed oxidative olefination to afford (2-acetoxymethyl)isoquinolines bearing an ortho-olefinated aryl group via a sequence that involves (1) Rh(III)-catalyzed alkyne cyclization with intramolecular 1,3-acetoxyl migration and (2) isoquinoline-directed ortho C-H olefination.
Links
MeSH
Pub Type(s)
Journal Article
Research Support, Non-U.S. Gov't
Language
eng
PubMed ID
22690947
Citation
Zhao, Peng, et al. "Rhodium(III)-catalyzed Cyclization-olefination of N-acetoxyl Ketoimine-alkynes." Organic Letters, vol. 14, no. 13, 2012, pp. 3400-3.
Zhao P, Wang F, Han K, et al. Rhodium(III)-catalyzed cyclization-olefination of N-acetoxyl ketoimine-alkynes. Org Lett. 2012;14(13):3400-3.
Zhao, P., Wang, F., Han, K., & Li, X. (2012). Rhodium(III)-catalyzed cyclization-olefination of N-acetoxyl ketoimine-alkynes. Organic Letters, 14(13), 3400-3. https://doi.org/10.1021/ol301371p
Zhao P, et al. Rhodium(III)-catalyzed Cyclization-olefination of N-acetoxyl Ketoimine-alkynes. Org Lett. 2012 Jul 6;14(13):3400-3. PubMed PMID: 22690947.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR
T1 - Rhodium(III)-catalyzed cyclization-olefination of N-acetoxyl ketoimine-alkynes.
AU - Zhao,Peng,
AU - Wang,Fen,
AU - Han,Keli,
AU - Li,Xingwei,
Y1 - 2012/06/12/
PY - 2012/6/14/entrez
PY - 2012/6/14/pubmed
PY - 2012/11/8/medline
SP - 3400
EP - 3
JF - Organic letters
JO - Org Lett
VL - 14
IS - 13
N2 - N-Acetoxyl ketoimine-alkynes undergo Rh(III)-catalyzed oxidative olefination to afford (2-acetoxymethyl)isoquinolines bearing an ortho-olefinated aryl group via a sequence that involves (1) Rh(III)-catalyzed alkyne cyclization with intramolecular 1,3-acetoxyl migration and (2) isoquinoline-directed ortho C-H olefination.
SN - 1523-7052
UR - https://www.unboundmedicine.com/medline/citation/22690947/Rhodium_III__catalyzed_cyclization_olefination_of_N_acetoxyl_ketoimine_alkynes_
L2 - https://doi.org/10.1021/ol301371p
DB - PRIME
DP - Unbound Medicine
ER -