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Rhodium(III)-catalyzed cyclization-olefination of N-acetoxyl ketoimine-alkynes.
Org Lett. 2012 Jul 06; 14(13):3400-3.OL

Abstract

N-Acetoxyl ketoimine-alkynes undergo Rh(III)-catalyzed oxidative olefination to afford (2-acetoxymethyl)isoquinolines bearing an ortho-olefinated aryl group via a sequence that involves (1) Rh(III)-catalyzed alkyne cyclization with intramolecular 1,3-acetoxyl migration and (2) isoquinoline-directed ortho C-H olefination.

Authors+Show Affiliations

Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China.No affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

22690947

Citation

Zhao, Peng, et al. "Rhodium(III)-catalyzed Cyclization-olefination of N-acetoxyl Ketoimine-alkynes." Organic Letters, vol. 14, no. 13, 2012, pp. 3400-3.
Zhao P, Wang F, Han K, et al. Rhodium(III)-catalyzed cyclization-olefination of N-acetoxyl ketoimine-alkynes. Org Lett. 2012;14(13):3400-3.
Zhao, P., Wang, F., Han, K., & Li, X. (2012). Rhodium(III)-catalyzed cyclization-olefination of N-acetoxyl ketoimine-alkynes. Organic Letters, 14(13), 3400-3. https://doi.org/10.1021/ol301371p
Zhao P, et al. Rhodium(III)-catalyzed Cyclization-olefination of N-acetoxyl Ketoimine-alkynes. Org Lett. 2012 Jul 6;14(13):3400-3. PubMed PMID: 22690947.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Rhodium(III)-catalyzed cyclization-olefination of N-acetoxyl ketoimine-alkynes. AU - Zhao,Peng, AU - Wang,Fen, AU - Han,Keli, AU - Li,Xingwei, Y1 - 2012/06/12/ PY - 2012/6/14/entrez PY - 2012/6/14/pubmed PY - 2012/11/8/medline SP - 3400 EP - 3 JF - Organic letters JO - Org Lett VL - 14 IS - 13 N2 - N-Acetoxyl ketoimine-alkynes undergo Rh(III)-catalyzed oxidative olefination to afford (2-acetoxymethyl)isoquinolines bearing an ortho-olefinated aryl group via a sequence that involves (1) Rh(III)-catalyzed alkyne cyclization with intramolecular 1,3-acetoxyl migration and (2) isoquinoline-directed ortho C-H olefination. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/22690947/Rhodium_III__catalyzed_cyclization_olefination_of_N_acetoxyl_ketoimine_alkynes_ L2 - https://doi.org/10.1021/ol301371p DB - PRIME DP - Unbound Medicine ER -