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Palladium(0)-catalyzed dearomative arylation of indoles: convenient access to spiroindolenine derivatives.
Org Lett. 2012 Jul 20; 14(14):3772-5.OL

Abstract

Dearomatization of an indole via palladium(0)-catalyzed cross-coupling reaction has been realized. With readily available triphenylphosphine as ligand, various spiroindolenine derivatives have been obtained in good to excellent yields, and enantioselective control is also feasible with chiral ligands.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Wu KJ
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Lingling Lu, Shanghai 200032, China.
Dai LX
No affiliation info available
You SL
No affiliation info available

MeSH

CatalysisIndolesLigandsMolecular StructurePalladiumSpiro CompoundsStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

22783995

Citation

Wu, Ke-Jia, et al. "Palladium(0)-catalyzed Dearomative Arylation of Indoles: Convenient Access to Spiroindolenine Derivatives." Organic Letters, vol. 14, no. 14, 2012, pp. 3772-5.
Wu KJ, Dai LX, You SL. Palladium(0)-catalyzed dearomative arylation of indoles: convenient access to spiroindolenine derivatives. Org Lett. 2012;14(14):3772-5.
Wu, K. J., Dai, L. X., & You, S. L. (2012). Palladium(0)-catalyzed dearomative arylation of indoles: convenient access to spiroindolenine derivatives. Organic Letters, 14(14), 3772-5. https://doi.org/10.1021/ol301663h
Wu KJ, Dai LX, You SL. Palladium(0)-catalyzed Dearomative Arylation of Indoles: Convenient Access to Spiroindolenine Derivatives. Org Lett. 2012 Jul 20;14(14):3772-5. PubMed PMID: 22783995.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Palladium(0)-catalyzed dearomative arylation of indoles: convenient access to spiroindolenine derivatives. AU - Wu,Ke-Jia, AU - Dai,Li-Xin, AU - You,Shu-Li, Y1 - 2012/07/12/ PY - 2012/7/13/entrez PY - 2012/7/13/pubmed PY - 2014/5/23/medline SP - 3772 EP - 5 JF - Organic letters JO - Org Lett VL - 14 IS - 14 N2 - Dearomatization of an indole via palladium(0)-catalyzed cross-coupling reaction has been realized. With readily available triphenylphosphine as ligand, various spiroindolenine derivatives have been obtained in good to excellent yields, and enantioselective control is also feasible with chiral ligands. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/22783995/Palladium_0__catalyzed_dearomative_arylation_of_indoles:_convenient_access_to_spiroindolenine_derivatives_ L2 - https://doi.org/10.1021/ol301663h DB - PRIME DP - Unbound Medicine ER -