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Organic acid induced olefination reaction of lactones.
Chem Commun (Camb). 2012 Sep 14; 48(71):8967-9.CC

Abstract

(Z)-Selective olefination of several lactones with ketene silyl acetals was achieved by the catalysis of carbon acids (C-H acids) having a bis(triflyl)methyl group as an acidic functionality; in particular, the triple carbon acid having three bis(triflyl)methyl groups in phloroglucinol shows an excellent catalytic performance.

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Authors+Show Affiliations

Yanai H
School of Pharmacy, Tokyo University of Pharmacy and Life Sciences, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, Japan. yanai@toyaku.ac.jp
Taguchi T
No affiliation info available

MeSH

AcetalsAlkenesCarbonic AcidCatalysisEthylenesKetonesLactonesStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

22850596

Citation

Yanai, Hikaru, and Takeo Taguchi. "Organic Acid Induced Olefination Reaction of Lactones." Chemical Communications (Cambridge, England), vol. 48, no. 71, 2012, pp. 8967-9.
Yanai H, Taguchi T. Organic acid induced olefination reaction of lactones. Chem Commun (Camb). 2012;48(71):8967-9.
Yanai, H., & Taguchi, T. (2012). Organic acid induced olefination reaction of lactones. Chemical Communications (Cambridge, England), 48(71), 8967-9. https://doi.org/10.1039/c2cc33606e
Yanai H, Taguchi T. Organic Acid Induced Olefination Reaction of Lactones. Chem Commun (Camb). 2012 Sep 14;48(71):8967-9. PubMed PMID: 22850596.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Organic acid induced olefination reaction of lactones. AU - Yanai,Hikaru, AU - Taguchi,Takeo, Y1 - 2012/07/31/ PY - 2012/8/2/entrez PY - 2012/8/2/pubmed PY - 2012/12/13/medline SP - 8967 EP - 9 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) VL - 48 IS - 71 N2 - (Z)-Selective olefination of several lactones with ketene silyl acetals was achieved by the catalysis of carbon acids (C-H acids) having a bis(triflyl)methyl group as an acidic functionality; in particular, the triple carbon acid having three bis(triflyl)methyl groups in phloroglucinol shows an excellent catalytic performance. SN - 1364-548X UR - https://www.unboundmedicine.com/medline/citation/22850596/Organic_acid_induced_olefination_reaction_of_lactones_ L2 - https://doi.org/10.1039/c2cc33606e DB - PRIME DP - Unbound Medicine ER -