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Liquid chromatographic/electrospray ionization tandem mass spectrometric study of polyphenolic composition of four cultivars of Fragaria vesca L. berries and their comparative evaluation.
J Mass Spectrom. 2012 Sep; 47(9):1207-20.JM

Abstract

High-performance liquid chromatography coupled with ion spray mass spectrometry in the tandem mode with both negative and positive ionization was used for investigating a variety of polyphenolic compounds in four genotypes of Fragaria vesca berries. About 60 phenolic compounds belonging to the compound classes of phenolic acids, ellagitannins, ellagic acid derivatives, flavonols, monomeric and oligomeric flavanols, dihydrochalcones and anthocyanins were reported, providing for the first time a quite complete picture of polyphenolic composition of F. vesca berries. Some of the polyphenols herein investigated, such as a tris-galloyl-hexahydroxydiphenoyl-hexose, two castalagin/vescalagin-like isomers and peonidin-malonylglucoside, were described for the first time. Principal component analysis applied on original HPLC-MS/MS data, acquired in multiple reaction monitoring mode, successfully discriminated the four investigated cultivars on the basis of their polyphenolic composition, highlighting the fundamental role of mass spectrometry for food characterization.

Authors+Show Affiliations

Department of Chemistry, Via della Lastruccia, 3-50019, Sesto Fiorentino, Florence, Italy.No affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article

Language

eng

PubMed ID

22972789

Citation

Del Bubba, Massimo, et al. "Liquid Chromatographic/electrospray Ionization Tandem Mass Spectrometric Study of Polyphenolic Composition of Four Cultivars of Fragaria Vesca L. Berries and Their Comparative Evaluation." Journal of Mass Spectrometry : JMS, vol. 47, no. 9, 2012, pp. 1207-20.
Del Bubba M, Checchini L, Chiuminatto U, et al. Liquid chromatographic/electrospray ionization tandem mass spectrometric study of polyphenolic composition of four cultivars of Fragaria vesca L. berries and their comparative evaluation. J Mass Spectrom. 2012;47(9):1207-20.
Del Bubba, M., Checchini, L., Chiuminatto, U., Doumett, S., Fibbi, D., & Giordani, E. (2012). Liquid chromatographic/electrospray ionization tandem mass spectrometric study of polyphenolic composition of four cultivars of Fragaria vesca L. berries and their comparative evaluation. Journal of Mass Spectrometry : JMS, 47(9), 1207-20. https://doi.org/10.1002/jms.3030
Del Bubba M, et al. Liquid Chromatographic/electrospray Ionization Tandem Mass Spectrometric Study of Polyphenolic Composition of Four Cultivars of Fragaria Vesca L. Berries and Their Comparative Evaluation. J Mass Spectrom. 2012;47(9):1207-20. PubMed PMID: 22972789.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Liquid chromatographic/electrospray ionization tandem mass spectrometric study of polyphenolic composition of four cultivars of Fragaria vesca L. berries and their comparative evaluation. AU - Del Bubba,Massimo, AU - Checchini,Leonardo, AU - Chiuminatto,Ugo, AU - Doumett,Saer, AU - Fibbi,Donatella, AU - Giordani,Edgardo, PY - 2012/9/14/entrez PY - 2012/9/14/pubmed PY - 2013/1/25/medline SP - 1207 EP - 20 JF - Journal of mass spectrometry : JMS JO - J Mass Spectrom VL - 47 IS - 9 N2 - High-performance liquid chromatography coupled with ion spray mass spectrometry in the tandem mode with both negative and positive ionization was used for investigating a variety of polyphenolic compounds in four genotypes of Fragaria vesca berries. About 60 phenolic compounds belonging to the compound classes of phenolic acids, ellagitannins, ellagic acid derivatives, flavonols, monomeric and oligomeric flavanols, dihydrochalcones and anthocyanins were reported, providing for the first time a quite complete picture of polyphenolic composition of F. vesca berries. Some of the polyphenols herein investigated, such as a tris-galloyl-hexahydroxydiphenoyl-hexose, two castalagin/vescalagin-like isomers and peonidin-malonylglucoside, were described for the first time. Principal component analysis applied on original HPLC-MS/MS data, acquired in multiple reaction monitoring mode, successfully discriminated the four investigated cultivars on the basis of their polyphenolic composition, highlighting the fundamental role of mass spectrometry for food characterization. SN - 1096-9888 UR - https://www.unboundmedicine.com/medline/citation/22972789/Liquid_chromatographic/electrospray_ionization_tandem_mass_spectrometric_study_of_polyphenolic_composition_of_four_cultivars_of_Fragaria_vesca_L__berries_and_their_comparative_evaluation_ L2 - https://doi.org/10.1002/jms.3030 DB - PRIME DP - Unbound Medicine ER -