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Comparison of various organic compounds destruction on rare earths doped Ti/Sb-SnO2 electrodes.
J Hazard Mater. 2012 Nov 15; 239-240:225-32.JH

Abstract

Ti/Sb-SnO2 and three kinds of rare earths (REs), namely Ce, Gd, and Eu doped Ti/Sb-SnO2 electrodes were prepared and tested for their capacity on electrocatalytic degradation of three kinds of basal aromatic compounds (benzoquinone, hydroquinone and catechol) and six kinds of aliphatic acids (maleic acid, fumaric acid, succinic acid, malonic acid, oxalic acid and acetic acid). The elimination of selected organics as well as their TOC removal with different doped Ti/Sb-SnO2 electrodes was described by first-order kinetics. Compared with Ti/Sb-SnO2, the Gd and Eu doped electrodes show better performance on the degradation of most of the selected organics, while Ce doped electrode shows either closely or lower efficiency on the degradation of these selected organics. Besides electrode material, the molecular structure of organic compound has obvious effect on its degradation in the electrocatalytic process. Catechol is more resistant to the electrophilic attack by hydroxyl radicals than benzoquinone and hydroquinone. The compound with more complicate molecular structure or longer carbon chain is more difficult to be mineralized. The aliphatic acid with higher oxygen content or more double bonds is more readily to be oxidized in the electrocatalytic process.

Authors+Show Affiliations

School of Environmental Science and Engineering, Huazhong University of Science and Technology, No. 1037 Luoyu Road, Hongshan District, Wuhan 430074, PR China.No affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

23022412

Citation

Cui, Yu-Hong, et al. "Comparison of Various Organic Compounds Destruction On Rare Earths Doped Ti/Sb-SnO2 Electrodes." Journal of Hazardous Materials, vol. 239-240, 2012, pp. 225-32.
Cui YH, Feng YJ, Liu J, et al. Comparison of various organic compounds destruction on rare earths doped Ti/Sb-SnO2 electrodes. J Hazard Mater. 2012;239-240:225-32.
Cui, Y. H., Feng, Y. J., Liu, J., & Ren, N. (2012). Comparison of various organic compounds destruction on rare earths doped Ti/Sb-SnO2 electrodes. Journal of Hazardous Materials, 239-240, 225-32. https://doi.org/10.1016/j.jhazmat.2012.08.068
Cui YH, et al. Comparison of Various Organic Compounds Destruction On Rare Earths Doped Ti/Sb-SnO2 Electrodes. J Hazard Mater. 2012 Nov 15;239-240:225-32. PubMed PMID: 23022412.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Comparison of various organic compounds destruction on rare earths doped Ti/Sb-SnO2 electrodes. AU - Cui,Yu-Hong, AU - Feng,Yu-Jie, AU - Liu,Junfeng, AU - Ren,Nanqi, Y1 - 2012/09/04/ PY - 2012/02/26/received PY - 2012/08/27/revised PY - 2012/08/28/accepted PY - 2012/10/2/entrez PY - 2012/10/2/pubmed PY - 2013/3/21/medline SP - 225 EP - 32 JF - Journal of hazardous materials JO - J. Hazard. Mater. VL - 239-240 N2 - Ti/Sb-SnO2 and three kinds of rare earths (REs), namely Ce, Gd, and Eu doped Ti/Sb-SnO2 electrodes were prepared and tested for their capacity on electrocatalytic degradation of three kinds of basal aromatic compounds (benzoquinone, hydroquinone and catechol) and six kinds of aliphatic acids (maleic acid, fumaric acid, succinic acid, malonic acid, oxalic acid and acetic acid). The elimination of selected organics as well as their TOC removal with different doped Ti/Sb-SnO2 electrodes was described by first-order kinetics. Compared with Ti/Sb-SnO2, the Gd and Eu doped electrodes show better performance on the degradation of most of the selected organics, while Ce doped electrode shows either closely or lower efficiency on the degradation of these selected organics. Besides electrode material, the molecular structure of organic compound has obvious effect on its degradation in the electrocatalytic process. Catechol is more resistant to the electrophilic attack by hydroxyl radicals than benzoquinone and hydroquinone. The compound with more complicate molecular structure or longer carbon chain is more difficult to be mineralized. The aliphatic acid with higher oxygen content or more double bonds is more readily to be oxidized in the electrocatalytic process. SN - 1873-3336 UR - https://www.unboundmedicine.com/medline/citation/23022412/Comparison_of_various_organic_compounds_destruction_on_rare_earths_doped_Ti/Sb_SnO2_electrodes_ L2 - https://linkinghub.elsevier.com/retrieve/pii/S0304-3894(12)00883-7 DB - PRIME DP - Unbound Medicine ER -