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Mechanistic insights into a supramolecular self-assembling catalyst system: evidence for hydrogen bonding during rhodium-catalyzed hydroformylation.
Angew Chem Int Ed Engl. 2012 Oct 29; 51(44):11033-8.AC

Abstract

The structural integrity and flexibility provided by intermolecular hydrogen bonds leads to the outstanding properties of the 6-diphenylphosphinopyridin-(2H)-1-one ligand (see scheme) in the rhodium-catalyzed hydroformylation of terminal alkenes, as demonstrated by the combination of spectroscopic methods and DFT computations. Hydrogen bonds were also detected in a competent intermediate of the catalytic cycle.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Gellrich U
Institut für Organische Chemie und Biochemie, Freiburg Institute for Advanced Studies (FRIAS), Albert-Ludwigs-Universität Freiburg, Albertstrasse 21, 79104 Freiburg i. Brsg., Germany.
Seiche W
No affiliation info available
Keller M
No affiliation info available
Breit B
No affiliation info available

MeSH

AldehydesAlkenesCatalysisCrystallography, X-RayHydrogen BondingMacromolecular SubstancesModels, MolecularMolecular StructureQuantum TheoryRhodiumStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

23023718

Citation

Gellrich, Urs, et al. "Mechanistic Insights Into a Supramolecular Self-assembling Catalyst System: Evidence for Hydrogen Bonding During Rhodium-catalyzed Hydroformylation." Angewandte Chemie (International Ed. in English), vol. 51, no. 44, 2012, pp. 11033-8.
Gellrich U, Seiche W, Keller M, et al. Mechanistic insights into a supramolecular self-assembling catalyst system: evidence for hydrogen bonding during rhodium-catalyzed hydroformylation. Angew Chem Int Ed Engl. 2012;51(44):11033-8.
Gellrich, U., Seiche, W., Keller, M., & Breit, B. (2012). Mechanistic insights into a supramolecular self-assembling catalyst system: evidence for hydrogen bonding during rhodium-catalyzed hydroformylation. Angewandte Chemie (International Ed. in English), 51(44), 11033-8. https://doi.org/10.1002/anie.201203768
Gellrich U, et al. Mechanistic Insights Into a Supramolecular Self-assembling Catalyst System: Evidence for Hydrogen Bonding During Rhodium-catalyzed Hydroformylation. Angew Chem Int Ed Engl. 2012 Oct 29;51(44):11033-8. PubMed PMID: 23023718.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Mechanistic insights into a supramolecular self-assembling catalyst system: evidence for hydrogen bonding during rhodium-catalyzed hydroformylation. AU - Gellrich,Urs, AU - Seiche,Wolfgang, AU - Keller,Manfred, AU - Breit,Bernhard, Y1 - 2012/09/28/ PY - 2012/05/16/received PY - 2012/10/2/entrez PY - 2012/10/2/pubmed PY - 2013/1/23/medline SP - 11033 EP - 8 JF - Angewandte Chemie (International ed. in English) JO - Angew Chem Int Ed Engl VL - 51 IS - 44 N2 - The structural integrity and flexibility provided by intermolecular hydrogen bonds leads to the outstanding properties of the 6-diphenylphosphinopyridin-(2H)-1-one ligand (see scheme) in the rhodium-catalyzed hydroformylation of terminal alkenes, as demonstrated by the combination of spectroscopic methods and DFT computations. Hydrogen bonds were also detected in a competent intermediate of the catalytic cycle. SN - 1521-3773 UR - https://www.unboundmedicine.com/medline/citation/23023718/Mechanistic_insights_into_a_supramolecular_self_assembling_catalyst_system:_evidence_for_hydrogen_bonding_during_rhodium_catalyzed_hydroformylation_ L2 - https://doi.org/10.1002/anie.201203768 DB - PRIME DP - Unbound Medicine ER -