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Pyridine synthesis by reactions of allyl amines and alkynes proceeding through a Cu(OAc)2 oxidation and Rh(III)-catalyzed N-annulation sequence.
Chem Commun (Camb). 2012 Nov 28; 48(92):11334-6.CC

Abstract

A new methodology has been developed for the synthesis of pyridines from allyl amines and alkynes, which involves sequential Cu(II)-promoted dehydrogenation of the allylamine and Rh(III)-catalyzed N-annulation of the resulting α,β-unsaturated imine and alkyne.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Kim DS
Department of Chemistry, Yonsei University, 50 Yonseiro, Seodaemun-gu, Seoul 120-749, Korea.
Park JW
No affiliation info available
Jun CH
No affiliation info available

MeSH

AcetatesAlkynesAminesCatalysisCopperCyclizationOxidation-ReductionPyridinesRhodium

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

23069867

Citation

Kim, Dong-Su, et al. "Pyridine Synthesis By Reactions of Allyl Amines and Alkynes Proceeding Through a Cu(OAc)2 Oxidation and Rh(III)-catalyzed N-annulation Sequence." Chemical Communications (Cambridge, England), vol. 48, no. 92, 2012, pp. 11334-6.
Kim DS, Park JW, Jun CH. Pyridine synthesis by reactions of allyl amines and alkynes proceeding through a Cu(OAc)2 oxidation and Rh(III)-catalyzed N-annulation sequence. Chem Commun (Camb). 2012;48(92):11334-6.
Kim, D. S., Park, J. W., & Jun, C. H. (2012). Pyridine synthesis by reactions of allyl amines and alkynes proceeding through a Cu(OAc)2 oxidation and Rh(III)-catalyzed N-annulation sequence. Chemical Communications (Cambridge, England), 48(92), 11334-6. https://doi.org/10.1039/c2cc36699a
Kim DS, Park JW, Jun CH. Pyridine Synthesis By Reactions of Allyl Amines and Alkynes Proceeding Through a Cu(OAc)2 Oxidation and Rh(III)-catalyzed N-annulation Sequence. Chem Commun (Camb). 2012 Nov 28;48(92):11334-6. PubMed PMID: 23069867.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Pyridine synthesis by reactions of allyl amines and alkynes proceeding through a Cu(OAc)2 oxidation and Rh(III)-catalyzed N-annulation sequence. AU - Kim,Dong-Su, AU - Park,Jung-Woo, AU - Jun,Chul-Ho, PY - 2012/10/17/entrez PY - 2012/10/17/pubmed PY - 2013/3/30/medline SP - 11334 EP - 6 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) VL - 48 IS - 92 N2 - A new methodology has been developed for the synthesis of pyridines from allyl amines and alkynes, which involves sequential Cu(II)-promoted dehydrogenation of the allylamine and Rh(III)-catalyzed N-annulation of the resulting α,β-unsaturated imine and alkyne. SN - 1364-548X UR - https://www.unboundmedicine.com/medline/citation/23069867/Pyridine_synthesis_by_reactions_of_allyl_amines_and_alkynes_proceeding_through_a_Cu_OAc_2_oxidation_and_Rh_III__catalyzed_N_annulation_sequence_ L2 - https://doi.org/10.1039/c2cc36699a DB - PRIME DP - Unbound Medicine ER -