Tags

Type your tag names separated by a space and hit enter

Iron-catalyzed dioxygen-driven C-C bond formation: oxidative dearomatization of 2-naphthols with construction of a chiral quaternary stereocenter.
J Am Chem Soc. 2012 Dec 12; 134(49):20017-20.JA

Abstract

Iron(salan) complex 1 was found to catalyze the oxidative dearomatization of 1-substituted 2-naphthols with the formation of an all-carbon quaternary stereocenter in air in the presence of nitroalkanes, to afford the corresponding cyclic enones with high enantioselectivity of 88-96% ee.

Links

Publisher Full Text (DOI)

Authors+Show Affiliations

Oguma T
Department of Chemistry, Graduate School of Science, and International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan.
Katsuki T
No affiliation info available

MeSH

CatalysisFerrous CompoundsModels, MolecularMolecular StructureNaphtholsOxidation-ReductionOxygen

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

23181470

Citation

Oguma, Takuya, and Tsutomu Katsuki. "Iron-catalyzed Dioxygen-driven C-C Bond Formation: Oxidative Dearomatization of 2-naphthols With Construction of a Chiral Quaternary Stereocenter." Journal of the American Chemical Society, vol. 134, no. 49, 2012, pp. 20017-20.
Oguma T, Katsuki T. Iron-catalyzed dioxygen-driven C-C bond formation: oxidative dearomatization of 2-naphthols with construction of a chiral quaternary stereocenter. J Am Chem Soc. 2012;134(49):20017-20.
Oguma, T., & Katsuki, T. (2012). Iron-catalyzed dioxygen-driven C-C bond formation: oxidative dearomatization of 2-naphthols with construction of a chiral quaternary stereocenter. Journal of the American Chemical Society, 134(49), 20017-20. https://doi.org/10.1021/ja310203c
Oguma T, Katsuki T. Iron-catalyzed Dioxygen-driven C-C Bond Formation: Oxidative Dearomatization of 2-naphthols With Construction of a Chiral Quaternary Stereocenter. J Am Chem Soc. 2012 Dec 12;134(49):20017-20. PubMed PMID: 23181470.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Iron-catalyzed dioxygen-driven C-C bond formation: oxidative dearomatization of 2-naphthols with construction of a chiral quaternary stereocenter. AU - Oguma,Takuya, AU - Katsuki,Tsutomu, Y1 - 2012/11/30/ PY - 2012/11/28/entrez PY - 2012/11/28/pubmed PY - 2013/6/6/medline SP - 20017 EP - 20 JF - Journal of the American Chemical Society JO - J Am Chem Soc VL - 134 IS - 49 N2 - Iron(salan) complex 1 was found to catalyze the oxidative dearomatization of 1-substituted 2-naphthols with the formation of an all-carbon quaternary stereocenter in air in the presence of nitroalkanes, to afford the corresponding cyclic enones with high enantioselectivity of 88-96% ee. SN - 1520-5126 UR - https://www.unboundmedicine.com/medline/citation/23181470/Iron_catalyzed_dioxygen_driven_C_C_bond_formation:_oxidative_dearomatization_of_2_naphthols_with_construction_of_a_chiral_quaternary_stereocenter_ L2 - https://doi.org/10.1021/ja310203c DB - PRIME DP - Unbound Medicine ER -