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Ruthenium-catalyzed pyrrole synthesis via oxidative annulation of enamides and alkynes.
Org Lett. 2013 Jan 04; 15(1):136-9.OL

Abstract

An efficient and regioselective ruthenium-catalyzed oxidative annulation of enamides with alkynes via the cleavage of C(sp(2))-H/N-H bonds is reported. The reactions can afford N-acetyl substituted or N-unsubstituted pyrroles by altering the reaction conditions slightly.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Li B
State Key Laboratory of Element-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, PR China. nklibin@nankai.edu.cn
Wang N
No affiliation info available
Liang Y
No affiliation info available
Xu S
No affiliation info available
Wang B
No affiliation info available

MeSH

AlkynesAmidesCatalysisCyclizationMolecular StructureOxidation-ReductionPyrrolesRutheniumStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

23234540

Citation

Li, Bin, et al. "Ruthenium-catalyzed Pyrrole Synthesis Via Oxidative Annulation of Enamides and Alkynes." Organic Letters, vol. 15, no. 1, 2013, pp. 136-9.
Li B, Wang N, Liang Y, et al. Ruthenium-catalyzed pyrrole synthesis via oxidative annulation of enamides and alkynes. Org Lett. 2013;15(1):136-9.
Li, B., Wang, N., Liang, Y., Xu, S., & Wang, B. (2013). Ruthenium-catalyzed pyrrole synthesis via oxidative annulation of enamides and alkynes. Organic Letters, 15(1), 136-9. https://doi.org/10.1021/ol303159h
Li B, et al. Ruthenium-catalyzed Pyrrole Synthesis Via Oxidative Annulation of Enamides and Alkynes. Org Lett. 2013 Jan 4;15(1):136-9. PubMed PMID: 23234540.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Ruthenium-catalyzed pyrrole synthesis via oxidative annulation of enamides and alkynes. AU - Li,Bin, AU - Wang,Nuancheng, AU - Liang,Yujie, AU - Xu,Shansheng, AU - Wang,Baiquan, Y1 - 2012/12/12/ PY - 2012/12/14/entrez PY - 2012/12/14/pubmed PY - 2013/5/29/medline SP - 136 EP - 9 JF - Organic letters JO - Org Lett VL - 15 IS - 1 N2 - An efficient and regioselective ruthenium-catalyzed oxidative annulation of enamides with alkynes via the cleavage of C(sp(2))-H/N-H bonds is reported. The reactions can afford N-acetyl substituted or N-unsubstituted pyrroles by altering the reaction conditions slightly. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/23234540/Ruthenium_catalyzed_pyrrole_synthesis_via_oxidative_annulation_of_enamides_and_alkynes_ L2 - https://doi.org/10.1021/ol303159h DB - PRIME DP - Unbound Medicine ER -