Tags

Type your tag names separated by a space and hit enter

Enantioselective synthesis of planar chiral ferrocenes via palladium-catalyzed direct coupling with arylboronic acids.
J Am Chem Soc. 2013 Jan 09; 135(1):86-9.JA

Abstract

Enantioselective Pd(II)-catalyzed direct coupling of aminomethylferrocene derivatives with boronic acids was realized. With commercially available Boc-L-Val-OH as a ligand, planar-chiral ferrocenes could be synthesized in yields of 14-81% with up to 99% ee under mild conditions.

Links

Publisher Full Text (DOI)

Authors+Show Affiliations

Gao DW
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, PR China.
Shi YC
No affiliation info available
Gu Q
No affiliation info available
Zhao ZL
No affiliation info available
You SL
No affiliation info available

MeSH

Boronic AcidsCatalysisFerrous CompoundsMetallocenesMolecular StructureOrganometallic CompoundsPalladiumStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

23253097

Citation

Gao, De-Wei, et al. "Enantioselective Synthesis of Planar Chiral Ferrocenes Via Palladium-catalyzed Direct Coupling With Arylboronic Acids." Journal of the American Chemical Society, vol. 135, no. 1, 2013, pp. 86-9.
Gao DW, Shi YC, Gu Q, et al. Enantioselective synthesis of planar chiral ferrocenes via palladium-catalyzed direct coupling with arylboronic acids. J Am Chem Soc. 2013;135(1):86-9.
Gao, D. W., Shi, Y. C., Gu, Q., Zhao, Z. L., & You, S. L. (2013). Enantioselective synthesis of planar chiral ferrocenes via palladium-catalyzed direct coupling with arylboronic acids. Journal of the American Chemical Society, 135(1), 86-9. https://doi.org/10.1021/ja311082u
Gao DW, et al. Enantioselective Synthesis of Planar Chiral Ferrocenes Via Palladium-catalyzed Direct Coupling With Arylboronic Acids. J Am Chem Soc. 2013 Jan 9;135(1):86-9. PubMed PMID: 23253097.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Enantioselective synthesis of planar chiral ferrocenes via palladium-catalyzed direct coupling with arylboronic acids. AU - Gao,De-Wei, AU - Shi,Yan-Chao, AU - Gu,Qing, AU - Zhao,Zheng-Le, AU - You,Shu-Li, Y1 - 2012/12/26/ PY - 2012/12/21/entrez PY - 2012/12/21/pubmed PY - 2013/6/6/medline SP - 86 EP - 9 JF - Journal of the American Chemical Society JO - J Am Chem Soc VL - 135 IS - 1 N2 - Enantioselective Pd(II)-catalyzed direct coupling of aminomethylferrocene derivatives with boronic acids was realized. With commercially available Boc-L-Val-OH as a ligand, planar-chiral ferrocenes could be synthesized in yields of 14-81% with up to 99% ee under mild conditions. SN - 1520-5126 UR - https://www.unboundmedicine.com/medline/citation/23253097/Enantioselective_synthesis_of_planar_chiral_ferrocenes_via_palladium_catalyzed_direct_coupling_with_arylboronic_acids_ L2 - https://doi.org/10.1021/ja311082u DB - PRIME DP - Unbound Medicine ER -