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Ozonation of iodide-containing waters: selective oxidation of iodide to iodate with simultaneous minimization of bromate and I-THMs.
Water Res. 2013 Apr 15; 47(6):1953-60.WR

Abstract

The presence of iodinated disinfection by-products (I-DBPs) in drinking water poses a potential health concern since it has been shown that I-DBPs are generally more genotoxic and cytotoxic than their chlorinated and brominated analogs. I-DBPs are formed during oxidation/disinfection of iodide-containing waters by reaction of the transient hypoiodous acid (HOI) with natural organic matter (NOM). In this study, we demonstrate that ozone pre-treatment selectively oxidizes iodide to iodate and avoids the formation of I-DBPs. Iodate is non-toxic and is therefore a desired sink of iodine in drinking water. Complete conversion of iodide to iodate while minimizing the bromate formation to below the guideline value of 10 μg L⁻¹ was achieved for a wide range of ozone doses in five raw waters with DOC and bromide concentrations of 1.1-20 mg L⁻¹ and 170-940 μg L⁻¹, respectively. Lowering the pH effectively further reduced bromate formation but had no impact on the extent of iodate and bromoform formation (the main trihalomethane (THM) formed during ozonation). Experiments carried out with pre-chlorinated/post-clarified samples already containing I-DBPs, showed that ozonation effectively oxidized I-THMs. Therefore, in iodide-containing waters, in which I-DBPs can be produced upon chlorination or especially chloramination, a pre-ozonation step to oxidize iodide to iodate is an efficient process to mitigate I-DBP formation.

Authors+Show Affiliations

Curtin Water Quality Research Centre, Department of Chemistry, Curtin University, Kent Street Bentley, WA 6102, Australia.No affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

23351431

Citation

Allard, S, et al. "Ozonation of Iodide-containing Waters: Selective Oxidation of Iodide to Iodate With Simultaneous Minimization of Bromate and I-THMs." Water Research, vol. 47, no. 6, 2013, pp. 1953-60.
Allard S, Nottle CE, Chan A, et al. Ozonation of iodide-containing waters: selective oxidation of iodide to iodate with simultaneous minimization of bromate and I-THMs. Water Res. 2013;47(6):1953-60.
Allard, S., Nottle, C. E., Chan, A., Joll, C., & von Gunten, U. (2013). Ozonation of iodide-containing waters: selective oxidation of iodide to iodate with simultaneous minimization of bromate and I-THMs. Water Research, 47(6), 1953-60. https://doi.org/10.1016/j.watres.2012.12.002
Allard S, et al. Ozonation of Iodide-containing Waters: Selective Oxidation of Iodide to Iodate With Simultaneous Minimization of Bromate and I-THMs. Water Res. 2013 Apr 15;47(6):1953-60. PubMed PMID: 23351431.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Ozonation of iodide-containing waters: selective oxidation of iodide to iodate with simultaneous minimization of bromate and I-THMs. AU - Allard,S, AU - Nottle,C E, AU - Chan,A, AU - Joll,C, AU - von Gunten,U, Y1 - 2012/12/10/ PY - 2012/07/20/received PY - 2012/11/30/revised PY - 2012/12/01/accepted PY - 2013/1/29/entrez PY - 2013/1/29/pubmed PY - 2013/8/29/medline SP - 1953 EP - 60 JF - Water research JO - Water Res. VL - 47 IS - 6 N2 - The presence of iodinated disinfection by-products (I-DBPs) in drinking water poses a potential health concern since it has been shown that I-DBPs are generally more genotoxic and cytotoxic than their chlorinated and brominated analogs. I-DBPs are formed during oxidation/disinfection of iodide-containing waters by reaction of the transient hypoiodous acid (HOI) with natural organic matter (NOM). In this study, we demonstrate that ozone pre-treatment selectively oxidizes iodide to iodate and avoids the formation of I-DBPs. Iodate is non-toxic and is therefore a desired sink of iodine in drinking water. Complete conversion of iodide to iodate while minimizing the bromate formation to below the guideline value of 10 μg L⁻¹ was achieved for a wide range of ozone doses in five raw waters with DOC and bromide concentrations of 1.1-20 mg L⁻¹ and 170-940 μg L⁻¹, respectively. Lowering the pH effectively further reduced bromate formation but had no impact on the extent of iodate and bromoform formation (the main trihalomethane (THM) formed during ozonation). Experiments carried out with pre-chlorinated/post-clarified samples already containing I-DBPs, showed that ozonation effectively oxidized I-THMs. Therefore, in iodide-containing waters, in which I-DBPs can be produced upon chlorination or especially chloramination, a pre-ozonation step to oxidize iodide to iodate is an efficient process to mitigate I-DBP formation. SN - 1879-2448 UR - https://www.unboundmedicine.com/medline/citation/23351431/Ozonation_of_iodide_containing_waters:_selective_oxidation_of_iodide_to_iodate_with_simultaneous_minimization_of_bromate_and_I_THMs_ L2 - https://linkinghub.elsevier.com/retrieve/pii/S0043-1354(12)00869-X DB - PRIME DP - Unbound Medicine ER -