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A chiral ruthenium-monophosphine catalyst for asymmetric addition of arylboronic acids to aryl aldehydes.
J Org Chem. 2013 Jun 21; 78(12):6350-5.JO

Abstract

A novel ruthenium catalyst on the basis of a chiral monophosphorus ligand is efficient for the asymmetric addition of arylboronic acids to aryl aldehydes, providing a series of chiral diarylmethanols in excellent yields and enantioselectivities (up to 92% ee). Preliminary study has shown that this process is catalyzed by a Ru complex with a single monophosphorus ligand.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Li K
Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, China.
Hu N
No affiliation info available
Luo R
No affiliation info available
Yuan W
No affiliation info available
Tang W
No affiliation info available

MeSH

AldehydesBoronic AcidsCatalysisPhosphinesRutheniumStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

23705850

Citation

Li, Ke, et al. "A Chiral Ruthenium-monophosphine Catalyst for Asymmetric Addition of Arylboronic Acids to Aryl Aldehydes." The Journal of Organic Chemistry, vol. 78, no. 12, 2013, pp. 6350-5.
Li K, Hu N, Luo R, et al. A chiral ruthenium-monophosphine catalyst for asymmetric addition of arylboronic acids to aryl aldehydes. J Org Chem. 2013;78(12):6350-5.
Li, K., Hu, N., Luo, R., Yuan, W., & Tang, W. (2013). A chiral ruthenium-monophosphine catalyst for asymmetric addition of arylboronic acids to aryl aldehydes. The Journal of Organic Chemistry, 78(12), 6350-5. https://doi.org/10.1021/jo400850m
Li K, et al. A Chiral Ruthenium-monophosphine Catalyst for Asymmetric Addition of Arylboronic Acids to Aryl Aldehydes. J Org Chem. 2013 Jun 21;78(12):6350-5. PubMed PMID: 23705850.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - A chiral ruthenium-monophosphine catalyst for asymmetric addition of arylboronic acids to aryl aldehydes. AU - Li,Ke, AU - Hu,Naifu, AU - Luo,Renshi, AU - Yuan,Weicheng, AU - Tang,Wenjun, Y1 - 2013/06/07/ PY - 2013/5/28/entrez PY - 2013/5/28/pubmed PY - 2014/1/17/medline SP - 6350 EP - 5 JF - The Journal of organic chemistry JO - J Org Chem VL - 78 IS - 12 N2 - A novel ruthenium catalyst on the basis of a chiral monophosphorus ligand is efficient for the asymmetric addition of arylboronic acids to aryl aldehydes, providing a series of chiral diarylmethanols in excellent yields and enantioselectivities (up to 92% ee). Preliminary study has shown that this process is catalyzed by a Ru complex with a single monophosphorus ligand. SN - 1520-6904 UR - https://www.unboundmedicine.com/medline/citation/23705850/A_chiral_ruthenium_monophosphine_catalyst_for_asymmetric_addition_of_arylboronic_acids_to_aryl_aldehydes_ L2 - https://doi.org/10.1021/jo400850m DB - PRIME DP - Unbound Medicine ER -