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Regioselective C2 Oxidative Olefination of Indoles and Pyrroles through Cationic Rhodium(III)-Catalyzed C-H Bond Activation.
Chemistry. 2013 Sep 02; 19(36):11863-8.C

Abstract

Be economic with your atoms! An efficient Rh-catalyzed oxidative olefination of indoles and pyrroles with broad substrate scope and tolerance is reported. The catalytic reaction proceeds with excellent regio- and stereoselectivity. The directing group N,N-dimethylcarbamoyl was crucial for the reaction and could be removed easily.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Li B
State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071 (China), Fax: (+86) 22-2350-4781. nklibin@nankai.edu.cn.
Ma J
No affiliation info available
Xie W
No affiliation info available
Song H
No affiliation info available
Xu S
No affiliation info available
Wang B
No affiliation info available

Pub Type(s)

Journal Article

Language

eng

PubMed ID

23881838

Citation

Li, Bin, et al. "Regioselective C2 Oxidative Olefination of Indoles and Pyrroles Through Cationic Rhodium(III)-Catalyzed C-H Bond Activation." Chemistry (Weinheim an Der Bergstrasse, Germany), vol. 19, no. 36, 2013, pp. 11863-8.
Li B, Ma J, Xie W, et al. Regioselective C2 Oxidative Olefination of Indoles and Pyrroles through Cationic Rhodium(III)-Catalyzed C-H Bond Activation. Chemistry. 2013;19(36):11863-8.
Li, B., Ma, J., Xie, W., Song, H., Xu, S., & Wang, B. (2013). Regioselective C2 Oxidative Olefination of Indoles and Pyrroles through Cationic Rhodium(III)-Catalyzed C-H Bond Activation. Chemistry (Weinheim an Der Bergstrasse, Germany), 19(36), 11863-8. https://doi.org/10.1002/chem.201301987
Li B, et al. Regioselective C2 Oxidative Olefination of Indoles and Pyrroles Through Cationic Rhodium(III)-Catalyzed C-H Bond Activation. Chemistry. 2013 Sep 2;19(36):11863-8. PubMed PMID: 23881838.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Regioselective C2 Oxidative Olefination of Indoles and Pyrroles through Cationic Rhodium(III)-Catalyzed C-H Bond Activation. AU - Li,Bin, AU - Ma,Jianfeng, AU - Xie,Weijia, AU - Song,Haibin, AU - Xu,Shansheng, AU - Wang,Baiquan, Y1 - 2013/07/23/ PY - 2013/05/23/received PY - 2013/7/25/entrez PY - 2013/7/25/pubmed PY - 2013/7/25/medline KW - CH activation KW - homogeneous catalysis KW - indoles KW - oxidative olefination KW - rhodium SP - 11863 EP - 8 JF - Chemistry (Weinheim an der Bergstrasse, Germany) JO - Chemistry VL - 19 IS - 36 N2 - Be economic with your atoms! An efficient Rh-catalyzed oxidative olefination of indoles and pyrroles with broad substrate scope and tolerance is reported. The catalytic reaction proceeds with excellent regio- and stereoselectivity. The directing group N,N-dimethylcarbamoyl was crucial for the reaction and could be removed easily. SN - 1521-3765 UR - https://www.unboundmedicine.com/medline/citation/23881838/Regioselective_C2_Oxidative_Olefination_of_Indoles_and_Pyrroles_through_Cationic_Rhodium_III__Catalyzed_C_H_Bond_Activation_ L2 - https://doi.org/10.1002/chem.201301987 DB - PRIME DP - Unbound Medicine ER -