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A convenient synthesis of quinolizinium salts through Rh(III) or Ru(II)-catalyzed C-H bond activation of 2-alkenylpyridines.
Chem Commun (Camb). 2013 Oct 04; 49(76):8528-30.CC

Abstract

An efficient synthesis of quinolizinium salts from 2-vinylpyridines and alkynes via Rh(III) or Ru(II)-catalyzed C-H activation and annulation reaction is described. A possible mechanism involving pyridine assisted vinylic ortho-C-H activation, alkyne insertion and reductive elimination is proposed.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Luo CZ
Department of Chemistry, National Tsing Hua University, Hsinchu 30013, Taiwan. chcheng@mx.nthu.edu.tw.
Gandeepan P
No affiliation info available
Cheng CH
No affiliation info available

MeSH

CatalysisMolecular StructureOrganometallic CompoundsPyridinesQuinolizinesRhodiumRutheniumSalts

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

23938459

Citation

Luo, Ching-Zong, et al. "A Convenient Synthesis of Quinolizinium Salts Through Rh(III) or Ru(II)-catalyzed C-H Bond Activation of 2-alkenylpyridines." Chemical Communications (Cambridge, England), vol. 49, no. 76, 2013, pp. 8528-30.
Luo CZ, Gandeepan P, Cheng CH. A convenient synthesis of quinolizinium salts through Rh(III) or Ru(II)-catalyzed C-H bond activation of 2-alkenylpyridines. Chem Commun (Camb). 2013;49(76):8528-30.
Luo, C. Z., Gandeepan, P., & Cheng, C. H. (2013). A convenient synthesis of quinolizinium salts through Rh(III) or Ru(II)-catalyzed C-H bond activation of 2-alkenylpyridines. Chemical Communications (Cambridge, England), 49(76), 8528-30. https://doi.org/10.1039/c3cc45004j
Luo CZ, Gandeepan P, Cheng CH. A Convenient Synthesis of Quinolizinium Salts Through Rh(III) or Ru(II)-catalyzed C-H Bond Activation of 2-alkenylpyridines. Chem Commun (Camb). 2013 Oct 4;49(76):8528-30. PubMed PMID: 23938459.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - A convenient synthesis of quinolizinium salts through Rh(III) or Ru(II)-catalyzed C-H bond activation of 2-alkenylpyridines. AU - Luo,Ching-Zong, AU - Gandeepan,Parthasarathy, AU - Cheng,Chien-Hong, PY - 2013/8/14/entrez PY - 2013/8/14/pubmed PY - 2014/3/29/medline SP - 8528 EP - 30 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) VL - 49 IS - 76 N2 - An efficient synthesis of quinolizinium salts from 2-vinylpyridines and alkynes via Rh(III) or Ru(II)-catalyzed C-H activation and annulation reaction is described. A possible mechanism involving pyridine assisted vinylic ortho-C-H activation, alkyne insertion and reductive elimination is proposed. SN - 1364-548X UR - https://www.unboundmedicine.com/medline/citation/23938459/A_convenient_synthesis_of_quinolizinium_salts_through_Rh_III__or_Ru_II__catalyzed_C_H_bond_activation_of_2_alkenylpyridines_ L2 - https://doi.org/10.1039/c3cc45004j DB - PRIME DP - Unbound Medicine ER -