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P-chirogenic organocatalysts: application to the aza-Morita-Baylis-Hillman (aza-MBH) reaction of ketimines.
Chem Commun (Camb). 2013 Sep 28; 49(75):8392-4.CC

Abstract

The P-chirogenic organocatalysts were found to promote the enantioselective aza-Morita-Baylis-Hillman reaction of ketimines derived from acyclic α-keto esters. In the P-chirogenic organocatalyzed aza-MBH reactions, α,α-disubstituted α-amino acid derivatives were obtained in high yields with high enantioselectivities (up to 97% ee).

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Publisher Full Text (DOI)

Authors+Show Affiliations

Takizawa S
The Institute of Scientific and Industrial Research (ISIR), Osaka University, Mihogaoka, Ibaraki-shi, Osaka 567-0047, Japan. sasai@sanken.osaka-u.ac.jp.
Rémond E
No affiliation info available
Arteaga FA
No affiliation info available
Yoshida Y
No affiliation info available
Sridharan V
No affiliation info available
Bayardon J
No affiliation info available
Jugé S
No affiliation info available
Sasai H
No affiliation info available

MeSH

Amino AcidsCatalysisIminesNitrilesStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

23939137

Citation

Takizawa, Shinobu, et al. "P-chirogenic Organocatalysts: Application to the aza-Morita-Baylis-Hillman (aza-MBH) Reaction of Ketimines." Chemical Communications (Cambridge, England), vol. 49, no. 75, 2013, pp. 8392-4.
Takizawa S, Rémond E, Arteaga FA, et al. P-chirogenic organocatalysts: application to the aza-Morita-Baylis-Hillman (aza-MBH) reaction of ketimines. Chem Commun (Camb). 2013;49(75):8392-4.
Takizawa, S., Rémond, E., Arteaga, F. A., Yoshida, Y., Sridharan, V., Bayardon, J., Jugé, S., & Sasai, H. (2013). P-chirogenic organocatalysts: application to the aza-Morita-Baylis-Hillman (aza-MBH) reaction of ketimines. Chemical Communications (Cambridge, England), 49(75), 8392-4. https://doi.org/10.1039/c3cc44549f
Takizawa S, et al. P-chirogenic Organocatalysts: Application to the aza-Morita-Baylis-Hillman (aza-MBH) Reaction of Ketimines. Chem Commun (Camb). 2013 Sep 28;49(75):8392-4. PubMed PMID: 23939137.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - P-chirogenic organocatalysts: application to the aza-Morita-Baylis-Hillman (aza-MBH) reaction of ketimines. AU - Takizawa,Shinobu, AU - Rémond,Emmanuelle, AU - Arteaga,Fernando Arteaga, AU - Yoshida,Yasushi, AU - Sridharan,Vellaisamy, AU - Bayardon,Jérôme, AU - Jugé,Sylvain, AU - Sasai,Hiroaki, PY - 2013/8/14/entrez PY - 2013/8/14/pubmed PY - 2014/3/22/medline SP - 8392 EP - 4 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) VL - 49 IS - 75 N2 - The P-chirogenic organocatalysts were found to promote the enantioselective aza-Morita-Baylis-Hillman reaction of ketimines derived from acyclic α-keto esters. In the P-chirogenic organocatalyzed aza-MBH reactions, α,α-disubstituted α-amino acid derivatives were obtained in high yields with high enantioselectivities (up to 97% ee). SN - 1364-548X UR - https://www.unboundmedicine.com/medline/citation/23939137/P_chirogenic_organocatalysts:_application_to_the_aza_Morita_Baylis_Hillman__aza_MBH__reaction_of_ketimines_ DB - PRIME DP - Unbound Medicine ER -