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Determination of chlorophenols in water by headspace solid phase microextraction ion mobility spectrometry (HS-SPME-IMS).
Talanta. 2013 Sep 30; 114:176-82.T

Abstract

Chlorophenols (CPs) as persistent toxic compounds are of worldwide environmental concern. Usage of chlorinated phenols, especially pentachlorophenol (PCP), has been restricted or widely banned in many countries due to their possible adverse health effects even at low concentrations. Ion mobility spectrometry (IMS) has received increasing interest in environmental applications due to its unique characteristics, such as portability and speed of analysis. A range of sample introduction methods combined with IMS enable analysis from different environmental matrices. This study utilised headspace solid phase microextraction IMS (HS-SPME-IMS) in the determination of CPs from water samples. The extraction conditions were examined and the method was applied to real water samples. The developed method is suitable to detect CPs at milligram per liter level in water. Based on the results, SPME-IMS setup is feasible as an early warning system for water monitoring of pollutants present in drinking or surface water in case of environmental accidents or leakages.

Authors+Show Affiliations

Lappeenranta University of Technology, LUT School of Technology, Department of Energy and Environmental Technology, Laboratory of Green Chemistry, Sammonkatu 12, 50130 Mikkeli, Finland. sanna.holopainen@lut.fiNo affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

23953458

Citation

Holopainen, Sanna, et al. "Determination of Chlorophenols in Water By Headspace Solid Phase Microextraction Ion Mobility Spectrometry (HS-SPME-IMS)." Talanta, vol. 114, 2013, pp. 176-82.
Holopainen S, Luukkonen V, Nousiainen M, et al. Determination of chlorophenols in water by headspace solid phase microextraction ion mobility spectrometry (HS-SPME-IMS). Talanta. 2013;114:176-82.
Holopainen, S., Luukkonen, V., Nousiainen, M., & Sillanpää, M. (2013). Determination of chlorophenols in water by headspace solid phase microextraction ion mobility spectrometry (HS-SPME-IMS). Talanta, 114, 176-82. https://doi.org/10.1016/j.talanta.2013.04.023
Holopainen S, et al. Determination of Chlorophenols in Water By Headspace Solid Phase Microextraction Ion Mobility Spectrometry (HS-SPME-IMS). Talanta. 2013 Sep 30;114:176-82. PubMed PMID: 23953458.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Determination of chlorophenols in water by headspace solid phase microextraction ion mobility spectrometry (HS-SPME-IMS). AU - Holopainen,Sanna, AU - Luukkonen,Ville, AU - Nousiainen,Marjaana, AU - Sillanpää,Mika, Y1 - 2013/04/15/ PY - 2013/02/22/received PY - 2013/04/03/revised PY - 2013/04/08/accepted PY - 2013/8/20/entrez PY - 2013/8/21/pubmed PY - 2014/3/13/medline KW - 2,3,4, 6-TeCP KW - 2,3,4,6-tetrachlorophenol KW - 2,4,6-TCP KW - 2,4,6-trichlorophenol KW - CAR/PDMS KW - CP KW - CW/TPR KW - Carbowax/templated resin KW - Carboxen/polydimethylsiloxane KW - Chlorophenol KW - Chlorophenols KW - Environmental health KW - GC–MS KW - Gas chromatography–mass spectrometry KW - HF-LPME KW - HPLC KW - HS-SPME-IMS KW - Headspace solid phase microextraction KW - High performance liquid chromatography KW - Hollow fibre liquid phase microextraction KW - IMS KW - Ion mobility spectrometry KW - LC/ESI-IMS KW - LOD KW - Limit of detection KW - Liquid chromatography/electrospray ion mobility spectrometry KW - Mass flow controller KW - Mfc KW - PA KW - PCP KW - PDMS/DVB KW - PTFE KW - Pentachlorophenol KW - Polyacrylate KW - Polydimethylsiloxane/divinylbenzene KW - Polytetrafluoroethylene KW - RIN KW - Reactant ion negative KW - SBSE KW - SPME KW - Solid phase microextraction KW - Stir bar sorptive extraction KW - TD KW - Thermal desorption KW - UV-Vis KW - Ultraviolet-visible KW - Water quality SP - 176 EP - 82 JF - Talanta JO - Talanta VL - 114 N2 - Chlorophenols (CPs) as persistent toxic compounds are of worldwide environmental concern. Usage of chlorinated phenols, especially pentachlorophenol (PCP), has been restricted or widely banned in many countries due to their possible adverse health effects even at low concentrations. Ion mobility spectrometry (IMS) has received increasing interest in environmental applications due to its unique characteristics, such as portability and speed of analysis. A range of sample introduction methods combined with IMS enable analysis from different environmental matrices. This study utilised headspace solid phase microextraction IMS (HS-SPME-IMS) in the determination of CPs from water samples. The extraction conditions were examined and the method was applied to real water samples. The developed method is suitable to detect CPs at milligram per liter level in water. Based on the results, SPME-IMS setup is feasible as an early warning system for water monitoring of pollutants present in drinking or surface water in case of environmental accidents or leakages. SN - 1873-3573 UR - https://www.unboundmedicine.com/medline/citation/23953458/Determination_of_chlorophenols_in_water_by_headspace_solid_phase_microextraction_ion_mobility_spectrometry__HS_SPME_IMS__ L2 - https://linkinghub.elsevier.com/retrieve/pii/S0039-9140(13)00305-6 DB - PRIME DP - Unbound Medicine ER -