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Aerobic Ru-catalyzed direct C2-olefination of N-heteroarenes with alkenes directed by a removable N-dimethylcarbamoyl group.
Chem Commun (Camb). 2013 Oct 09; 49(78):8830-2.CC

Abstract

A highly efficient and selective Ru-catalyzed direct C2-olefination of indoles, pyrroles, and carbazoles assisted by a removable N-dimethylcarbamoyl group has been developed by using O2 as the terminal oxidant. Both electron-deficient and unactivated alkenes are applicable to the protocol.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Zhang LQ
Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University, 29 Wangjiang Road, Chengdu 610064, PR China. fsong@scu.edu.cn.
Yang S
No affiliation info available
Huang X
No affiliation info available
You J
No affiliation info available
Song F
No affiliation info available

MeSH

AlkenesCarbazolesCatalysisIndolesOxidantsOxygenPyrrolesRuthenium

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

23959021

Citation

Zhang, Luo-Qiang, et al. "Aerobic Ru-catalyzed Direct C2-olefination of N-heteroarenes With Alkenes Directed By a Removable N-dimethylcarbamoyl Group." Chemical Communications (Cambridge, England), vol. 49, no. 78, 2013, pp. 8830-2.
Zhang LQ, Yang S, Huang X, et al. Aerobic Ru-catalyzed direct C2-olefination of N-heteroarenes with alkenes directed by a removable N-dimethylcarbamoyl group. Chem Commun (Camb). 2013;49(78):8830-2.
Zhang, L. Q., Yang, S., Huang, X., You, J., & Song, F. (2013). Aerobic Ru-catalyzed direct C2-olefination of N-heteroarenes with alkenes directed by a removable N-dimethylcarbamoyl group. Chemical Communications (Cambridge, England), 49(78), 8830-2. https://doi.org/10.1039/c3cc44787a
Zhang LQ, et al. Aerobic Ru-catalyzed Direct C2-olefination of N-heteroarenes With Alkenes Directed By a Removable N-dimethylcarbamoyl Group. Chem Commun (Camb). 2013 Oct 9;49(78):8830-2. PubMed PMID: 23959021.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Aerobic Ru-catalyzed direct C2-olefination of N-heteroarenes with alkenes directed by a removable N-dimethylcarbamoyl group. AU - Zhang,Luo-Qiang, AU - Yang,Shiping, AU - Huang,Xiaolei, AU - You,Jingsong, AU - Song,Feijie, PY - 2013/8/21/entrez PY - 2013/8/21/pubmed PY - 2014/3/25/medline SP - 8830 EP - 2 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) VL - 49 IS - 78 N2 - A highly efficient and selective Ru-catalyzed direct C2-olefination of indoles, pyrroles, and carbazoles assisted by a removable N-dimethylcarbamoyl group has been developed by using O2 as the terminal oxidant. Both electron-deficient and unactivated alkenes are applicable to the protocol. SN - 1364-548X UR - https://www.unboundmedicine.com/medline/citation/23959021/Aerobic_Ru_catalyzed_direct_C2_olefination_of_N_heteroarenes_with_alkenes_directed_by_a_removable_N_dimethylcarbamoyl_group_ L2 - https://doi.org/10.1039/c3cc44787a DB - PRIME DP - Unbound Medicine ER -