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Enantioselective synthesis of 3-hydroxy oxindoles by ytterbium-catalysed decarboxylative addition of β-ketoacids to isatins.
Org Biomol Chem. 2013 Oct 14; 11(38):6456-9.OB

Abstract

A ytterbium(III)-indapybox catalysed enantioselective decarboxylative addition reaction of β-ketoacids to isatins is described. The biologically important 3-hydroxy oxindoles were obtained in high yields and excellent enantioselectivities.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Duan Z
School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, China. yiwang@nju.edu.cn.
Han J
No affiliation info available
Qian P
No affiliation info available
Zhang Z
No affiliation info available
Wang Y
No affiliation info available
Pan Y
No affiliation info available

MeSH

CatalysisDecarboxylationIndolesIsatinKeto AcidsModels, MolecularMolecular StructureOrganometallic CompoundsStereoisomerismYtterbium

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

23979548

Citation

Duan, Zhiqiang, et al. "Enantioselective Synthesis of 3-hydroxy Oxindoles By Ytterbium-catalysed Decarboxylative Addition of Β-ketoacids to Isatins." Organic & Biomolecular Chemistry, vol. 11, no. 38, 2013, pp. 6456-9.
Duan Z, Han J, Qian P, et al. Enantioselective synthesis of 3-hydroxy oxindoles by ytterbium-catalysed decarboxylative addition of β-ketoacids to isatins. Org Biomol Chem. 2013;11(38):6456-9.
Duan, Z., Han, J., Qian, P., Zhang, Z., Wang, Y., & Pan, Y. (2013). Enantioselective synthesis of 3-hydroxy oxindoles by ytterbium-catalysed decarboxylative addition of β-ketoacids to isatins. Organic & Biomolecular Chemistry, 11(38), 6456-9. https://doi.org/10.1039/c3ob41460d
Duan Z, et al. Enantioselective Synthesis of 3-hydroxy Oxindoles By Ytterbium-catalysed Decarboxylative Addition of Β-ketoacids to Isatins. Org Biomol Chem. 2013 Oct 14;11(38):6456-9. PubMed PMID: 23979548.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Enantioselective synthesis of 3-hydroxy oxindoles by ytterbium-catalysed decarboxylative addition of β-ketoacids to isatins. AU - Duan,Zhiqiang, AU - Han,Jianlin, AU - Qian,Ping, AU - Zhang,Zirui, AU - Wang,Yi, AU - Pan,Yi, Y1 - 2013/08/27/ PY - 2013/8/28/entrez PY - 2013/8/28/pubmed PY - 2014/5/7/medline SP - 6456 EP - 9 JF - Organic & biomolecular chemistry JO - Org Biomol Chem VL - 11 IS - 38 N2 - A ytterbium(III)-indapybox catalysed enantioselective decarboxylative addition reaction of β-ketoacids to isatins is described. The biologically important 3-hydroxy oxindoles were obtained in high yields and excellent enantioselectivities. SN - 1477-0539 UR - https://www.unboundmedicine.com/medline/citation/23979548/Enantioselective_synthesis_of_3_hydroxy_oxindoles_by_ytterbium_catalysed_decarboxylative_addition_of_β_ketoacids_to_isatins_ L2 - https://doi.org/10.1039/c3ob41460d DB - PRIME DP - Unbound Medicine ER -