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De novo synthesis of polysubstituted naphthols and furans using photoredox neutral coupling of alkynes with 2-bromo-1,3-dicarbonyl compounds.
Org Lett. 2013 Sep 20; 15(18):4884-7.OL

Abstract

A conceptually new strategy has been described for the mild, practical, and environmentally friendly preparation of naphthols and furans using a visible-light promoted photoredox neutral approach. These reactions between accessible electron-deficient bromides and commercially available alkynes could be carried out at room temperature in good-to-excellent chemical yields without any external stoichiometric oxidants.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Jiang H
State Key Laboratory of Analytical Chemistry for Life Science and Institute of Chemical Biology and Drug Innovation, School of Chemistry and Chemical Engineering, Nanjing University , Nanjing, 210093, China.
Cheng Y
No affiliation info available
Zhang Y
No affiliation info available
Yu S
No affiliation info available

MeSH

AlkynesCatalysisFuransHydrocarbons, BrominatedMolecular StructureNaphtholsOxidation-Reduction

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

24000895

Citation

Jiang, Heng, et al. "De Novo Synthesis of Polysubstituted Naphthols and Furans Using Photoredox Neutral Coupling of Alkynes With 2-bromo-1,3-dicarbonyl Compounds." Organic Letters, vol. 15, no. 18, 2013, pp. 4884-7.
Jiang H, Cheng Y, Zhang Y, et al. De novo synthesis of polysubstituted naphthols and furans using photoredox neutral coupling of alkynes with 2-bromo-1,3-dicarbonyl compounds. Org Lett. 2013;15(18):4884-7.
Jiang, H., Cheng, Y., Zhang, Y., & Yu, S. (2013). De novo synthesis of polysubstituted naphthols and furans using photoredox neutral coupling of alkynes with 2-bromo-1,3-dicarbonyl compounds. Organic Letters, 15(18), 4884-7. https://doi.org/10.1021/ol402325z
Jiang H, et al. De Novo Synthesis of Polysubstituted Naphthols and Furans Using Photoredox Neutral Coupling of Alkynes With 2-bromo-1,3-dicarbonyl Compounds. Org Lett. 2013 Sep 20;15(18):4884-7. PubMed PMID: 24000895.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - De novo synthesis of polysubstituted naphthols and furans using photoredox neutral coupling of alkynes with 2-bromo-1,3-dicarbonyl compounds. AU - Jiang,Heng, AU - Cheng,Yuanzheng, AU - Zhang,Yan, AU - Yu,Shouyun, Y1 - 2013/09/03/ PY - 2013/9/5/entrez PY - 2013/9/5/pubmed PY - 2014/3/1/medline SP - 4884 EP - 7 JF - Organic letters JO - Org Lett VL - 15 IS - 18 N2 - A conceptually new strategy has been described for the mild, practical, and environmentally friendly preparation of naphthols and furans using a visible-light promoted photoredox neutral approach. These reactions between accessible electron-deficient bromides and commercially available alkynes could be carried out at room temperature in good-to-excellent chemical yields without any external stoichiometric oxidants. SN - 1523-7052 UR - https://www.unboundmedicine.com/medline/citation/24000895/De_novo_synthesis_of_polysubstituted_naphthols_and_furans_using_photoredox_neutral_coupling_of_alkynes_with_2_bromo_13_dicarbonyl_compounds_ DB - PRIME DP - Unbound Medicine ER -