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Ruthenium-catalyzed regioselective C2 alkenylation of indoles and pyrroles via C-H bond functionalization.
J Org Chem. 2013 Sep 20; 78(18):9345-53.JO

Abstract

An efficient ruthenium-catalyzed oxidative coupling of indoles and pyrroles with various alkenes at the C2-position assisted by employing the N,N-dimethylcarbamoyl moiety as a directing group is reported. The catalytic reaction proceeds in an excellent regio- and stereoselective manner.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Li B
State Key Laboratory of Element-Organic Chemistry, Synergetic Innovation Center of Chemical Science and Engineering, College of Chemistry, Nankai University , Tianjin 300071, P. R. China.
Ma J
No affiliation info available
Xie W
No affiliation info available
Song H
No affiliation info available
Xu S
No affiliation info available
Wang B
No affiliation info available

MeSH

CatalysisIndolesMolecular StructureOrganometallic CompoundsPyrrolesRutheniumStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

24025192

Citation

Li, Bin, et al. "Ruthenium-catalyzed Regioselective C2 Alkenylation of Indoles and Pyrroles Via C-H Bond Functionalization." The Journal of Organic Chemistry, vol. 78, no. 18, 2013, pp. 9345-53.
Li B, Ma J, Xie W, et al. Ruthenium-catalyzed regioselective C2 alkenylation of indoles and pyrroles via C-H bond functionalization. J Org Chem. 2013;78(18):9345-53.
Li, B., Ma, J., Xie, W., Song, H., Xu, S., & Wang, B. (2013). Ruthenium-catalyzed regioselective C2 alkenylation of indoles and pyrroles via C-H bond functionalization. The Journal of Organic Chemistry, 78(18), 9345-53. https://doi.org/10.1021/jo401579m
Li B, et al. Ruthenium-catalyzed Regioselective C2 Alkenylation of Indoles and Pyrroles Via C-H Bond Functionalization. J Org Chem. 2013 Sep 20;78(18):9345-53. PubMed PMID: 24025192.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Ruthenium-catalyzed regioselective C2 alkenylation of indoles and pyrroles via C-H bond functionalization. AU - Li,Bin, AU - Ma,Jianfeng, AU - Xie,Weijia, AU - Song,Haibin, AU - Xu,Shansheng, AU - Wang,Baiquan, Y1 - 2013/09/11/ PY - 2013/9/13/entrez PY - 2013/9/13/pubmed PY - 2014/3/1/medline SP - 9345 EP - 53 JF - The Journal of organic chemistry JO - J Org Chem VL - 78 IS - 18 N2 - An efficient ruthenium-catalyzed oxidative coupling of indoles and pyrroles with various alkenes at the C2-position assisted by employing the N,N-dimethylcarbamoyl moiety as a directing group is reported. The catalytic reaction proceeds in an excellent regio- and stereoselective manner. SN - 1520-6904 UR - https://www.unboundmedicine.com/medline/citation/24025192/Ruthenium_catalyzed_regioselective_C2_alkenylation_of_indoles_and_pyrroles_via_C_H_bond_functionalization_ L2 - https://doi.org/10.1021/jo401579m DB - PRIME DP - Unbound Medicine ER -