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Spiro[4,4]-1,6-nonadiene-based diphosphine oxides in lewis base catalyzed asymmetric double-aldol reactions.
Angew Chem Int Ed Engl. 2013 Oct 11; 52(42):11054-8.AC

Abstract

Symmetry swap: A C2 -chiral spiro diphosphine oxide (SpinPO) has been found to be highly efficient and enantioselective in the catalysis of double-aldol reactions of ketones and aldehydes to give the corresponding optically active double-aldol products, which can be readily transformed into optically active C3 - and pseudo-C3 -symmetric molecules.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Zhang P
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, 345 Lingling Road, Shanghai 200032 (P. R. China).
Han Z
No affiliation info available
Wang Z
No affiliation info available
Ding K
No affiliation info available

MeSH

AldehydesAlkadienesCatalysisLewis BasesMolecular StructureOxidesPhosphinesSpiro CompoundsStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

24038632

Citation

Zhang, Panke, et al. "Spiro[4,4]-1,6-nonadiene-based Diphosphine Oxides in Lewis Base Catalyzed Asymmetric Double-aldol Reactions." Angewandte Chemie (International Ed. in English), vol. 52, no. 42, 2013, pp. 11054-8.
Zhang P, Han Z, Wang Z, et al. Spiro[4,4]-1,6-nonadiene-based diphosphine oxides in lewis base catalyzed asymmetric double-aldol reactions. Angew Chem Int Ed Engl. 2013;52(42):11054-8.
Zhang, P., Han, Z., Wang, Z., & Ding, K. (2013). Spiro[4,4]-1,6-nonadiene-based diphosphine oxides in lewis base catalyzed asymmetric double-aldol reactions. Angewandte Chemie (International Ed. in English), 52(42), 11054-8. https://doi.org/10.1002/anie.201305846
Zhang P, et al. Spiro[4,4]-1,6-nonadiene-based Diphosphine Oxides in Lewis Base Catalyzed Asymmetric Double-aldol Reactions. Angew Chem Int Ed Engl. 2013 Oct 11;52(42):11054-8. PubMed PMID: 24038632.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Spiro[4,4]-1,6-nonadiene-based diphosphine oxides in lewis base catalyzed asymmetric double-aldol reactions. AU - Zhang,Panke, AU - Han,Zhaobin, AU - Wang,Zheng, AU - Ding,Kuiling, Y1 - 2013/08/27/ PY - 2013/07/05/received PY - 2013/9/17/entrez PY - 2013/9/17/pubmed PY - 2014/6/6/medline KW - aldol reactions KW - asymmetric catalysis KW - organocatalysis KW - phosphine oxide KW - spiro compounds SP - 11054 EP - 8 JF - Angewandte Chemie (International ed. in English) JO - Angew Chem Int Ed Engl VL - 52 IS - 42 N2 - Symmetry swap: A C2 -chiral spiro diphosphine oxide (SpinPO) has been found to be highly efficient and enantioselective in the catalysis of double-aldol reactions of ketones and aldehydes to give the corresponding optically active double-aldol products, which can be readily transformed into optically active C3 - and pseudo-C3 -symmetric molecules. SN - 1521-3773 UR - https://www.unboundmedicine.com/medline/citation/24038632/Spiro[44]_16_nonadiene_based_diphosphine_oxides_in_lewis_base_catalyzed_asymmetric_double_aldol_reactions_ L2 - https://doi.org/10.1002/anie.201305846 DB - PRIME DP - Unbound Medicine ER -