Rhodium-catalyzed synthesis of isoquinolines and indenes from benzylidenehydrazones and internal alkynes.J Org Chem. 2014 Feb 07; 79(3):1025-31.JO
Abstract
A new route is presented for the selective assembly of isoquinolines and indenes by rhodium-catalyzed tandem cyclization of benzylidenehydrazones with internal alkynes. This method involves the selective cleavage of the N-N bond and the C═N bonds and is dependent on the substituents of the benzylidenehydrazone.
Links
Pub Type(s)
Journal Article
Research Support, Non-U.S. Gov't
Language
eng
PubMed ID
24417252
Citation
Huang, Xiao-Cheng, et al. "Rhodium-catalyzed Synthesis of Isoquinolines and Indenes From Benzylidenehydrazones and Internal Alkynes." The Journal of Organic Chemistry, vol. 79, no. 3, 2014, pp. 1025-31.
Huang XC, Yang XH, Song RJ, et al. Rhodium-catalyzed synthesis of isoquinolines and indenes from benzylidenehydrazones and internal alkynes. J Org Chem. 2014;79(3):1025-31.
Huang, X. C., Yang, X. H., Song, R. J., & Li, J. H. (2014). Rhodium-catalyzed synthesis of isoquinolines and indenes from benzylidenehydrazones and internal alkynes. The Journal of Organic Chemistry, 79(3), 1025-31. https://doi.org/10.1021/jo402497v
Huang XC, et al. Rhodium-catalyzed Synthesis of Isoquinolines and Indenes From Benzylidenehydrazones and Internal Alkynes. J Org Chem. 2014 Feb 7;79(3):1025-31. PubMed PMID: 24417252.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR
T1 - Rhodium-catalyzed synthesis of isoquinolines and indenes from benzylidenehydrazones and internal alkynes.
AU - Huang,Xiao-Cheng,
AU - Yang,Xu-Heng,
AU - Song,Ren-Jie,
AU - Li,Jin-Heng,
Y1 - 2014/01/16/
PY - 2014/1/15/entrez
PY - 2014/1/15/pubmed
PY - 2014/9/6/medline
SP - 1025
EP - 31
JF - The Journal of organic chemistry
JO - J Org Chem
VL - 79
IS - 3
N2 - A new route is presented for the selective assembly of isoquinolines and indenes by rhodium-catalyzed tandem cyclization of benzylidenehydrazones with internal alkynes. This method involves the selective cleavage of the N-N bond and the C═N bonds and is dependent on the substituents of the benzylidenehydrazone.
SN - 1520-6904
UR - https://www.unboundmedicine.com/medline/citation/24417252/Rhodium_catalyzed_synthesis_of_isoquinolines_and_indenes_from_benzylidenehydrazones_and_internal_alkynes_
L2 - https://doi.org/10.1021/jo402497v
DB - PRIME
DP - Unbound Medicine
ER -
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