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Rhodium-catalyzed synthesis of isoquinolines and indenes from benzylidenehydrazones and internal alkynes.
J Org Chem. 2014 Feb 07; 79(3):1025-31.JO

Abstract

A new route is presented for the selective assembly of isoquinolines and indenes by rhodium-catalyzed tandem cyclization of benzylidenehydrazones with internal alkynes. This method involves the selective cleavage of the N-N bond and the C═N bonds and is dependent on the substituents of the benzylidenehydrazone.

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Publisher Full Text (DOI)

Authors+Show Affiliations

Huang XC
State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University , Changsha 410082, China.
Yang XH
No affiliation info available
Song RJ
No affiliation info available
Li JH
No affiliation info available

MeSH

AlkynesCatalysisHydrazinesIndenesIsoquinolinesMolecular StructureRhodium

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

24417252

Citation

Huang, Xiao-Cheng, et al. "Rhodium-catalyzed Synthesis of Isoquinolines and Indenes From Benzylidenehydrazones and Internal Alkynes." The Journal of Organic Chemistry, vol. 79, no. 3, 2014, pp. 1025-31.
Huang XC, Yang XH, Song RJ, et al. Rhodium-catalyzed synthesis of isoquinolines and indenes from benzylidenehydrazones and internal alkynes. J Org Chem. 2014;79(3):1025-31.
Huang, X. C., Yang, X. H., Song, R. J., & Li, J. H. (2014). Rhodium-catalyzed synthesis of isoquinolines and indenes from benzylidenehydrazones and internal alkynes. The Journal of Organic Chemistry, 79(3), 1025-31. https://doi.org/10.1021/jo402497v
Huang XC, et al. Rhodium-catalyzed Synthesis of Isoquinolines and Indenes From Benzylidenehydrazones and Internal Alkynes. J Org Chem. 2014 Feb 7;79(3):1025-31. PubMed PMID: 24417252.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Rhodium-catalyzed synthesis of isoquinolines and indenes from benzylidenehydrazones and internal alkynes. AU - Huang,Xiao-Cheng, AU - Yang,Xu-Heng, AU - Song,Ren-Jie, AU - Li,Jin-Heng, Y1 - 2014/01/16/ PY - 2014/1/15/entrez PY - 2014/1/15/pubmed PY - 2014/9/6/medline SP - 1025 EP - 31 JF - The Journal of organic chemistry JO - J Org Chem VL - 79 IS - 3 N2 - A new route is presented for the selective assembly of isoquinolines and indenes by rhodium-catalyzed tandem cyclization of benzylidenehydrazones with internal alkynes. This method involves the selective cleavage of the N-N bond and the C═N bonds and is dependent on the substituents of the benzylidenehydrazone. SN - 1520-6904 UR - https://www.unboundmedicine.com/medline/citation/24417252/Rhodium_catalyzed_synthesis_of_isoquinolines_and_indenes_from_benzylidenehydrazones_and_internal_alkynes_ DB - PRIME DP - Unbound Medicine ER -