Cyclometalated [Cp*M(C^X)] (M = Ir, Rh; X = N, C, O, P) complexes.
Chem Soc Rev. 2014 Apr 21; 43(8):2799-823.CS

Abstract

Half-sandwich Cp*Ir and Cp*Rh metalacycles have been successfully applied in traditional domains encompassing organic transformations and catalysis in recent years, especially the catalytic activation of C-H bonds. Cyclometalation has proven to be a highly attractive and versatile synthetic method for the formation of organometallic metalacycles. This review intends to describe isolated and well-defined cyclometalated iridium/rhodium complexes that contain a Cp*M-C (M = Ir, Rh) bond stabilised by the intramolecular coordination of neutral donor atoms (N, C, O or P). The formation of metalamacrocycles and cages employing cyclometalated approaches is discussed. In focusing on selected mechanistic insights garnered from iridium/rhodium-catalysed functionalisation of C-H bonds involving cyclometalated complexes, a limited number of substrates will be discussed, but a broad range of mechanistic features is highlighted.

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Authors+Show Affiliations

Han YF

Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University, Shanghai, 200433, P. R. China. gxjin@fudan.edu.cn yfhan1980@fudan.edu.cn.

Jin GX

No affiliation info available

Pub Type(s)

Journal Article

Language

eng

PubMed ID

24500011

Citation

Han, Ying-Feng, and Guo-Xin Jin. "Cyclometalated [Cp*M(C^X)] (M = Ir, Rh; X = N, C, O, P) Complexes." Chemical Society Reviews, vol. 43, no. 8, 2014, pp. 2799-823.

Han YF, Jin GX. Cyclometalated [Cp*M(C^X)] (M = Ir, Rh; X = N, C, O, P) complexes. Chem Soc Rev. 2014;43(8):2799-823.

Han, Y. F., & Jin, G. X. (2014). Cyclometalated [Cp*M(C^X)] (M = Ir, Rh; X = N, C, O, P) complexes. Chemical Society Reviews, 43(8), 2799-823. https://doi.org/10.1039/c3cs60343a

Han YF, Jin GX. Cyclometalated [Cp*M(C^X)] (M = Ir, Rh; X = N, C, O, P) Complexes. Chem Soc Rev. 2014 Apr 21;43(8):2799-823. PubMed PMID: 24500011.

* Article titles in AMA citation format should be in sentence-case

TY - JOUR T1 - Cyclometalated [Cp*M(C^X)] (M = Ir, Rh; X = N, C, O, P) complexes. AU - Han,Ying-Feng, AU - Jin,Guo-Xin, Y1 - 2014/02/05/ PY - 2014/2/7/entrez PY - 2014/2/7/pubmed PY - 2014/2/7/medline SP - 2799 EP - 823 JF - Chemical Society reviews JO - Chem Soc Rev VL - 43 IS - 8 N2 - Half-sandwich Cp*Ir and Cp*Rh metalacycles have been successfully applied in traditional domains encompassing organic transformations and catalysis in recent years, especially the catalytic activation of C-H bonds. Cyclometalation has proven to be a highly attractive and versatile synthetic method for the formation of organometallic metalacycles. This review intends to describe isolated and well-defined cyclometalated iridium/rhodium complexes that contain a Cp*M-C (M = Ir, Rh) bond stabilised by the intramolecular coordination of neutral donor atoms (N, C, O or P). The formation of metalamacrocycles and cages employing cyclometalated approaches is discussed. In focusing on selected mechanistic insights garnered from iridium/rhodium-catalysed functionalisation of C-H bonds involving cyclometalated complexes, a limited number of substrates will be discussed, but a broad range of mechanistic features is highlighted. SN - 1460-4744 UR - https://www.unboundmedicine.com/medline/citation/24500011/Cyclometalated_[Cp_M_C^X_]__M_=_Ir_Rh DB - PRIME DP - Unbound Medicine ER -

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Cyclometalated [Cp*M(C^X)] (M = Ir, Rh; X = N, C, O, P) complexes.Chem Soc Rev. 2014 Apr 21; 43(8):2799-823.CS